 Improved method for producing raw solder
专利摘要:
A pyrometallurgical process for producing raw solder from a base material is selected based on the levels of Sn, Cu, Sb, Bi, Zn, As, Ni and Pb, which comprises the steps of forming a liquid in an oven metal and slag bath, the introduction of a reducing agent and possibly energy, the separation of the crude solder from the slag and the removal of liquid from the furnace. Furthermore, a crude solder is disclosed with at least 9.5-69% by weight tin and at least 25% by weight lead, at least 80% tin and lead together, 0.08-12% by weight copper, 0.15% 7% antimony, 0.012-1.5% bismuth, 0.010-1.1% zinc, and up to 3% arsenic, 2.8% nickel, 0.7% zinc 7.5 wt% iron and 0.5 wt% aluminum. The solder can be smoothly processed to become suitable as a base material for vacuum distillation. 公开号:BE1025128B1 申请号:E20185240 申请日:2018-04-10 公开日:2018-11-16 发明作者:Valentin Casado；Luis Martinez；Bert Coletti；Jan Dirk A Goris；Visscher Yves De；Charles Geenen 申请人:Metallo Belgium； IPC主号:
专利说明:
(30) Priority data: 10/04/2017 EP 17165797.6 (73) Holder (s): METALLO BELGIUM 2340, BEERSE Belgium (72) Inventor (s): CASADO Valentin 48640 BERANGO Spain MARTINEZ Luis 48640 BERANGO Spain COLETTI Bert 3930ACHEL Belgium GORIS Jan Dirk A. 2340 BEERSE Belgium THE FISHERMAN Yves 2275 WECHELDERZANDE Belgium NO Charles 3900 OVERPEL Belgium (54) Improved method for producing raw solder (57) A pyrometallurgical method for producing raw solder from a base material selected on the basis of the contents of Sn, Cu, Sb, Bi, Zn, As, Ni and Pb, which includes the steps of forming a liquid metal and slag bath in an oven, introducing a reducing agent and optional energy, separating the raw solder from the slag and removing liquid from the oven. Furthermore, a raw solder is disclosed with at least 9.5-69 wt% tin and at least 25 wt% lead, at least 80% tin and lead combined, 0.08-12 wt% copper, 0.15- 7 wt% antimony, 0.012-1.5 wt% bismuth, 0.010-1.1 wt% zinc, and at most 3 wt. % arsenic, 2.8 wt% nickel, 0.7 wt% zinc, 7.5 wt% iron and 0.5 wt% aluminum. The solder can be worked smoothly to become suitable as a base material for vacuum distillation. Figure 1 BELGIAN INVENTION PATENT FPS Economy, K.M.O., Self-employed Publication number: 1025128 & Energy Submission number: BE2018 / 5240 Intellectual Property Office International classification: C22B 7/04 C22B 25/06 C22C 11/06 C22C 13/00 C22B 13/00 C22B 25/00 B23K 35/26 C22B 9/02 C22B 9/04 C22B 15/00 Date of grant: 16/11/2018 The Minister of Economy, Having regard to the Paris Convention of 20 March 1883 for the Protection of Industrial Property; Having regard to the Law of March 28, 1984 on inventive patents, Article 22, for patent applications filed before September 22, 2014; Having regard to Title 1 Invention Patents of Book XI of the Economic Law Code, Article XI.24, for patent applications filed from September 22, 2014; Having regard to the Royal Decree of 2 December 1986 on the filing, granting and maintenance of inventive patents, Article 28; Having regard to the application for an invention patent received by the Intellectual Property Office on 10/04/2018. Whereas for patent applications that fall within the scope of Title 1, Book XI, of the Code of Economic Law (hereinafter WER), in accordance with Article XI.19, § 4, second paragraph, of the WER, the granted patent will be limited. to the patent claims for which the novelty search report was prepared, when the patent application is the subject of a novelty search report indicating a lack of unity of invention as referred to in paragraph 1, and when the applicant does not limit his filing and does not file a divisional application in accordance with the search report. Decision: Article 1 METALLO BELGIUM, Nieuwe Dreef 33, 2340 BEERSE Belgium; represented by GEVERS PATENTS, Holidaystraat 5, 1831, DIEGEM; a Belgian invention patent with a term of 20 years, subject to payment of the annual fees as referred to in Article XI.48, § 1 of the Economic Law Code, for: Improved working method for the production of raw solder. INVENTOR (S): CASADO Valentin, c / o METALLO SPAIN Cmno Arana Bidea 20, 48640, BERANGO; MARTINEZ Luis, c / o METALLO SPAIN Cmno Arana Bidea 20, 48640, BERANGO; COLETTI Bert, Catherine Valley 1, 3930, ACHEL; GORIS Jan Dirk A., Patrijsstraat 17, 2340, BEERSE; THE FISHERMAN Yves, Wagemansstraat 64, 2275, WECHELDERZANDE; NO Charles, Willem II Street 27, 3900, OVERPEL; PRIORITY : 10/04/2017 EP 17165797.6; BREAKDOWN: Split from basic application: Filing date of the basic application: Article 2. - This patent is granted without prior investigation into the patentability of the invention, without warranty of the merit of the invention, nor of the accuracy of its description and at the risk of the applicant (s). Brussels, 16/11/2018, With special authorization: BE2018 / 5240 Improved method of producing raw solder FIELD OF THE INVENTION The present invention concerns the production of non-ferrous metals, in particular tin (Sn) and lead (Pb), optionally in combination with the production of copper (Cu), by Pyrometallurgy. More particularly, the invention relates to an improved method of producing a raw solder, a metal mixture mainly comprising tin and lead, which is particularly suitable for producing high quality products of high purity tin and / or lead. The present invention further relates to the raw solder itself and its use in the production of an improved solder composition. BACKGROUND OF THE INVENTION The materials available as a base material for producing non-ferrous metals usually contain a variety of metals. Due to the high purity requirements of the nonferrous metals when used in most of their high volume applications, the different metals need to be separated from each other in the production process. The non-ferrous metal production processes typically comprise at least one, and usually a plurality of pyrometallurgical process steps in which metals and metal oxides both occur in a liquid molten state, and wherein the metal oxides are gravitated as a separate and usually lighter liquid slag can be separated from the usually heavier molten metal phase. The slag is usually withdrawn from the process as a separate stream, and this separation can lead to slag production as a by-product of metal production. The non-ferrous metals can be produced from new ore as a starting material, also known as primary sources, or from recyclable materials, also called secondary raw materials, or from a combination thereof. Recyclable materials can BE2018 / 5240, for example, by-products, waste materials and end-of-life materials. The recovery of non-ferrous metals from secondary base materials has become an activity of the utmost importance over the years. The post-use recycling of non-ferrous metals has become a key factor in the industry due to the continued high demand for such metals and the diminishing availability of new, high-quality metal ores. Many of these secondary base materials are available in a finely divided form, for which the potential end uses are quite limited. The processing of secondary base materials typically involves the use of pyrometallurgical process steps that yield a slag as a by-product. In the production of copper concentrates by Pyrometallurgy, the tin and / or lead, if present, tends to become oxidized more easily than copper, and the oxides thereof easily end up in the supernatant slag. This slag can be separated from the copper-rich molten metal. By a subsequent chemical reduction step, the tin and / or lead in the slag can then be converted to their metal state, and these metals can then be separated from the rest of the slag as a molten metal mixture rich in tin and / or lead, and usually contains significant amounts of both. These metal streams generally have a lower melting point than the copper-containing by-products and are often referred to as "solder". In addition to the tin and lead, these brazing solder may contain significant but relatively smaller amounts of other metals, such as copper (Cu), antimony (Sb), arsenic (As), bismuth (Bi), iron (Fe), indium (In) , nickel (Ni), zinc (Zn), aluminum (Al), germanium (Ge), tellurium (Te), cobalt (Co), manganese (Mn), selenium (Se), silicon (Si), thallium (Tl) , gallium (Ga), and sometimes precious metals, albeit usually in much smaller quantities, such as silver (Ag), gold (Au), platinum (Pt), palladium (Pd), ruthenium (Ru), rhodium (Rh) , osmium (Os) and iridium (Ir). The raw solder may also include elements that are not considered to be metals, such as sulfur (S), carbon (C), and oxygen (O). BE2018 / 5240 The brazing may have direct commercial applications depending on their composition, but they are also known as an intermediate in the recovery of some of their individual components in a higher purity form suitable for producing concentrated metal products acceptable to are bred to their more demanding end applications. Mainly, there is still a high interest in recovering higher purity tin (Sn) from such brazing currents, as well as recovering lead (Pb) in some higher purity forms. US 4,508,565 discloses a process for producing lead having a sulfur content of 1.0% by weight from pellets formed from lead oxide-lead sulfate raw materials from copper conversion dust. The raw material contained 40 wt% lead, 12 wt% zinc, 3.5 wt% arsenic, 1.15 wt% copper, 8.0 wt% sulfur, 0.5 wt% bismuth and 0.6 wt% tin. About half of the pellets were loaded into a top blown Kaldo type rotary converter along with finely divided limestone granulated phayalite slag obtained from a copper production process and coke in particle sizes between 5 and 12 mm. This first furnace load was heated using an oil-oxygen burner to a doughy consistency, the second half of the pellets, additional amounts of limestone, phayalite slag, and coke were added, and heating was continued. From the converter were tapped: (i) a slag at 1120 ° C of 16.5% Zn, 18% Fe, 1.4% Pb, 1.4% As, 1.5% Sn, 20% SiO 2, 21 % CaO and 1.5% MgO, and (ii) the crude lead product containing 1.0% sulfur. US 4,508,565 does not address the production of a solder or the recovery of high purity metal streams therefrom. A well-known technique for obtaining higher purity metal streams from solder is the use of vacuum distillation, a technique usually performed under very low pressures in combination with relatively high temperatures. By means of vacuum distillation, lead can be separated by evaporation from other, BE2018 / 5240 less volatile metals, such as tin. Vacuum distillation can be used to separate a solder stream into a higher purity lead stream as the overhead product, and a higher purity tin stream as the residual bottoms product. The vacuum distillation of metal mixtures of the solder type can be carried out batchwise or in continuous mode. However, the inventors have found that the distillation of solder type metals can be plagued by operational problems. Over time, even at high temperatures, insoluble solids can form from the crystallization of metal-metal compounds containing copper, nickel, iron and / or zinc. These insoluble solids can adhere to the distillation equipment, especially in sensitive areas such as small openings, hindering smooth operation and even blocking the equipment. The inventors have found that specific metals are able, in vacuum distillation conditions, to form metal-metal bonds between at least two of these specific metals, and / or metal-metal compounds of at least one of the specific metals with tin. The inventors have further found that many of these metal-metal compounds have a much higher melting point than the temperature of the mixture in which they are formed. Accordingly, the inventors have found that these high melting point metal metal compounds can come out of solution and form solids. These solids can remain in suspension in the liquid metal and carry the risk of reducing the flowability of the mixture, for example, by increasing the viscosity of the liquid mixture. This in itself can hinder smooth operation of the distillation equipment, for example, by slowing the flow of liquid metals, which reduces the capacity of the equipment, so that the equipment must be used at a lower throughput. The solids can also adhere and / or get stuck to the distillation equipment, thereby posing a risk of hindering or even blocking the operation of the distillation equipment, for example by clogging important passages to the process streams. This BE2018 / 5240 phenomenon can even lead to the unplanned shutdown of the process, to open the distillation equipment and to clean or replace the affected parts. The inventors have found that in particular chromium (Cr), manganese (Mn), vanadium (V), titanium (Ti), tungsten (W), copper (Cu), nickel (Ni), iron (Fe), zinc ( Zn) and aluminum (Al) are metals whose presence in a brazing stream fed to a vacuum distillation step can lead to the troublesome metal-metal compounds. Cu, Ni, Fe, Zn and Al are quite often present in brazing streams from non-ferrous metal production, usually because of their presence in the starting materials. Fe and Al can also be added in the context of process steps prior to the production of the solder. The inventors have found that the problems identified can be significantly reduced and even avoided by controlling the concentration of these metals in the raw solder within specific limits. To remove these metals, the raw solder is usually pretreated, prior to vacuum distillation, by a rather complex process called "cupro process" or "silicon process", or more accurately "cup silicon process", which includes elemental silicon, which is also often Called "silicon metal", it is added in a form suitable for selectively reacting some of the metals (such as copper, nickel and iron) away from the lead and tin to form metal silicon alloys (silicide) or metal alloys. metal joints. Two immiscible metal phases are then formed, whereby the silicides are collected in the top layer, which is also referred to as the “cupro” material layer. When the reaction is complete, the temperature is lowered and the "cupro" layer solidifies first on top of the brazing metal phase, since the latter has the highest melting temperature. This "cupro" layer can then be removed from the still molten brazing metal phase on which it floats, for example by tapping the solder away from under the solidified BE2018 / 5240 cupro layer. After being subjected to the silicon process and cooling, the solder contains less copper, nickel, and / or iron, and is therefore more suitable for obtaining higher purity metal streams by vacuum distillation. U.S. Pat. No. 2,329,817 discloses such a process in which 36 parts by weight of silicon metal was added to 600 parts of a molten, impure "white metal" containing 5.27% Ni coated with 48 parts of a sodium silicate slag. After the reaction, 74.0 parts by weight of a silicide layer were formed 42.5 wt% Ni and only minor amounts of Sn, Pb, As and Sb. The remaining 552 parts by weight of the metal mixture contain only 0.13% by weight of nickel. However, such a process requires and consumes quite scarce, and therefore expensive, raw materials containing silicon metal, and which, after recycling the silicide formed in the silicon process, eventually ends up as oxides in low-grade by-product such as slag. This degradation of high-grade silicon metal to the much lower-grade slag represents a significant economic burden. Technically, aluminum could also be used in the cuprosilicon process, instead of - or together with silicon. The contaminating metals would then form aluminides, which would also be separated into the cup layer and thus removed. However, this is not done in practice. Aluminum poses the problem of forming aluminum antimonide and aluminum arsenide with antimony and arsenic under the conditions of the cuprous silicon process. These metal-metal compounds readily react with water after cooling, even under standard conditions, normal conditions and / or room conditions, where the moisture in the ambient air is sufficient to form the highly toxic gases stibine (SbH 3 ) or arsine (AsH 3 ), which fatal at very low concentrations in air. Since it is practically impossible to avoid these safety risks, the use of aluminum in the cuprous silicon process is not an option and is therefore excluded. GB 224923 discloses a treatment of a Cornish tin ore concentrate BE2018 / 5240 for producing a lead / tin alloy, a product of the solder type. The tin ore concentrate contained at least 15% tin, further contained arsenopyrites, and had a siliceous gangue as the non-valuable part of the concentrate. The tin ore concentrate was first roasted to remove the arsenic and to convert at least some of the iron sulfide in the pyrite to iron oxide. The roasted tin concentrate was mixed with a lead concentrate and the mixture was melted in a reverberation oven in a reducing atmosphere. There was a significant excess of lead with respect to tin, and the proportion of lead to tin in the charge was preferably 6 to 8 parts of lead with respect to 1 part of tin. Additional oxide of iron or other flux material may have been added to form a suitable slag. Iron in metal form, preferably tin scrap, was added to reduce the sulfide of lead and tin to the respective metals. The charge temperature was gradually increased, but it was prevented from rising to the temperature at which silicates are formed until the tin oxide had been converted to tin sulfide. When this conversion had taken place, the temperature was further raised to form a slag and complete the reduction of the sulfides of lead and tin. The cargo was then scooped off and tapped. A tin-lead alloy was found on the bottom of the bath, and this product was found suitable for use in producing various alloys of tin and lead, or to be subjected to any known complete or incomplete process separate the two metals. GB 224923 does not disclose any metals other than lead and tin that may have been present in the alloy product, such as excess iron, nor does it disclose how to separate lead and / or tin downstream from the solder type product, in which the ratio of lead to tin was 6: 1 to 8: 1. Consequently, there is still a need for a simple and cost effective method for producing a crude type of soldering flux, preferably from secondary base materials which may be (partly) finely divided, the crude solder being sufficiently rich in tin and lead, and sufficiently low in copper, nickel, iron and zinc, such that BE2018 / 5240 the composition, after only relatively simple chemical updating steps, is suitable for trouble-free vacuum distillation to separate lead from tin, more particularly without risk of metal-metal compound formation in the distillation equipment due to the presence of interfering amounts of copper, nickel, iron and zinc, without requiring the cuprous silicon process step as an essential additional processing step for conditioning the raw solder to a quality that does not lead to metal-metal bond formation during downstream vacuum distillation. A conventional apparatus for producing copper concentrate from copper-containing secondary base materials, in which raw solder is formed as a by-product, is a top-blown rotary converter (TBRC), also known as a Kaldo type furnace. This is an oven equipped to rotate about a longitudinal axis, but also equipped to rotate about a second horizontal axis perpendicular to that longitudinal axis. However, a TBRC is a complex and expensive device. In addition, if a portion of the base material is finely divided, much of this fine portion can be easily blown out of the TBRC by the flue gases typically produced inside before it has a chance of being incorporated into the liquid bath in the oven. This portion of the base material is lost to the process and can additionally pose a significant waste processing problem. There are alternatives to the TBRC, such as the so-called “Isasmelt” or “Ausmelt” devices for producing high-quality copper concentrate product from secondary base materials, but they are equally complex devices. Therefore, there is an additional need to simplify the method of solder production so that it can be run in a much less complex processing equipment, which is preferably also capable of accepting finely divided base materials without operational or waste handling problems cause. BE2018 / 5240 The present invention aims to overcome or at least alleviate the above-described problem and / or to provide improvements generally. SUMMARY OF THE INVENTION According to the invention, there is provided a method of producing a raw solder, a raw solder obtainable by the method, and the use of said raw solder, as defined in any of the appended claims. In one embodiment, the invention provides a method of producing a raw solder comprising lead (Pb) and tin (Sn) from a base material comprising at least 50% by weight of total metal, relative to the total dry weight of the base material the total base material comprising the following metals, the amounts of each metal being expressed as the total of the metal present in the base material in any oxidized state and in the reduced metal form, and relative to the total dry weight of the base material: • at least 2 wt% and at most 71 wt% tin (Sn), • at least 1.00 wt% and at most 10 wt% copper (Cu), • at least 0.02 wt% and at most 5 wt% antimony (Sb), • at least 0.0004 wt% and at most 1 wt% bismuth (Bi), • at most 37 wt% zinc (Zn), • at most 1 wt. % arsenic (As), and • at most 2 wt% nickel (Ni), the total base material further comprising lead (Pb) and characterized by a Pb / Sn weight ratio of at least 0.5 and at most 4, 0, and wherein at least one of tin (Sn) and lead (Pb) is at least partially present in an oxidized valent form, the method comprising the following steps: a) obtaining a liquid bath comprising a molten metal phase and / or a molten metal oxide slag in an oven by introducing at least a portion of the base material into the BE2018 / 5240 furnace and melting the added portion of the base material; b) introducing at least one reducing agent into the oven and reducing at least a portion of the oxidized valent form from tin and / or lead to tin and / or lead metal; c) optionally introducing into the furnace at least one energy source comprising a combustible material and / or comprising at least one metal less noble than Sn and Pb, and oxidizing the combustible material and / or the at least one metal into the energy source by injecting air and / or oxygen into the furnace; d) separating the crude solder obtained in step b) and / or c) from the slag and removing at least a portion of the crude solder and / or from the slag from the oven. In one embodiment, the invention provides a raw solder obtainable by the method of the present invention, which, in addition to unavoidable impurities and relative to the total dry weight of the raw solder, includes: • at least 9.5 wt% and at most 69 wt% tin (Sn), • at least 25 wt% lead (Pb), • at least 80 wt% tin (Sn) and lead (Pb) together , • at least 0.08 wt% and at most 12 wt% copper (Cu), • at least 0.15 wt% and at most 7 wt% antimony (Sb), • at least 0.012 wt% and at most 1.5 wt% bismuth (Bi), • at least 0.010 wt% and at most 1.1 wt% sulfur (S), • at most 3 wt% arsenic (As), • at most 2.8 wt% nickel (Ni), • at most 0.7 wt% zinc (Zn), • at most 7.5 wt% iron (Fe), and • at most 0.5 wt% aluminum (Already). In one embodiment, the method of the present invention is for producing the raw solder of the present invention. BE2018 / 5240 The brazing composition indicated above occurs either as a molten liquid phase at a temperature above 300 ° C or as a solid alloy at lower temperatures. The solid alloy may exceptionally be granulated or powdered, resulting in a particulate material, which can attract moisture in this form. For the sake of accuracy, the indicated concentrations in such a context are intended to represent values based on the total dry weight of the composition. The inventors have found that the selection of the base material for the process, as prescribed as part of the present invention, makes the process of the present invention suitable for producing a raw solder that can be smoothly advanced by simple process steps purified or "upgraded" to a grade suitable for trouble-free downstream vacuum distillation for the evaporation of lead from tin in the solder. The inventors have found that the raw solder obtainable by the method of the present invention contains the potentially interfering metals in concentrations such that the complex and expensive "cupro" process step, ie, a step in which silicon is added in an oxidizable form for forming silicides, where these silicides can be separated from the solder after cooling, thereby removing some of the potentially interfering metals, can be eliminated and omitted from the steps that prepare the raw solder as a raw material for the vacuum distillation. The inventors have found that a thorough selection of the base material of the method of the present invention allows the production of a raw solder containing amounts of the problematic metals which can be further reduced without the scarce and expensive raw metal silicon and / or aluminum are needed. In other words, the raw solder produced by the method of the present invention can be further conditioned to be suitable as BE2018 / 5240 raw material for vacuum distillation by chemical treatment steps other than treating with silicon and / or aluminum metal to form silicides and / or aluminides and selectively solidifying and removing these silicides and / or aluminides. The problematic metals are the metals that can form metal-metal compounds in vacuum distillation conditions, either by themselves, or with each other, or with tin. The list of problematic metals includes in particular chromium (Cr), manganese (Mn), vanadium (V), titanium (Ti), tungsten (W), copper (Cu), nickel (Ni), iron (Fe), zinc (Zn) and aluminum (Al). Several of these metals need not be taken into account, as they are usually very scarce in the raw materials used to produce the main non-ferrous metals containing lead and / or tin. The raw solder and the raw materials of the process of the present invention usually contain at most 0.10 wt% Cr, Mn, V, Ti or W, preferably at most 0.05 wt%, more preferably at most 0.010 wt%, even more preferably at most 0.005 wt%, preferably at most 0.0010 wt%, more preferably at most 0.0005 wt%, even more preferably at most 0.0001 wt% of any of Cr, Mn, V, Ti or W, relative to the total dry weight of the composition. The present invention is therefore mainly concerned with the contents of Cu, Ni, Fe, Zn and Al, since these metals can be quite commonly present in solder streams from the production of non-ferrous metal, usually because of their presence in the starting materials. Fe and Al can also be introduced as part of process steps upstream of the solder production. Applicants have found that the raw solder obtainable by the method of the present invention can be properly conditioned or updated to become a suitable base material for vacuum distillation using the treatment steps described in WO 2018/060202 A1. The inventors have further found that the potentially harmful metals, and in particular copper, are not complete BE2018 / 5240 should be removed from the raw solder to make this stream suitable, after further updating or treatment as mentioned above, for vacuum distillation. For example, the inventors have found that the identified problems can be reduced to a practical and economically acceptable level if small amounts of copper remain in the updated solder fed to the distillation step. This finding has the advantage that it is possible to process brazing currents that arise as the by-product of the recovery of copper from primary and / or secondary base materials, in particular from secondary base materials, and more importantly from base materials that finish at the end of their longevity. The inventors have found that the presence of some sulfur in the raw solder is advantageous. The sulfur aids in the downstream steps where Cu is removed from the raw solder, as part of the further upstream side effect of the vacuum distillation step. When S is within the prescribed limits, applicants have found that the downstream "updating" of the raw solder is facilitated and improved by reducing the amount of chemicals to be used. The inventors have found that more of the valuable tin can be recovered in the raw solder when the lead / tin ratio of the base material is at least 0.5 and at most 4.0. The inventors have found that when the base material contains more lead, the relative amount of tin in the raw solder relative to the amount of tin in the base material is also higher. The inventors have found that by providing more lead along with the tin, the recovery of tin from the base material is improved, and less of the available tin ends up in the slag. The amount of tin recovered usually makes the greatest contribution to the added value of the processing of the raw solder. The recovery of tin is therefore an important parameter of the process and is advantageously as high as economically and practically justifiable. BE2018 / 5240 We have found that the raw solder produced by the process of the present invention, after updating, can be smoothly subjected to a vacuum distillation step without the problem of metal-metal bond formation during vacuum distillation. The inventors have further found that the method of the present invention can be performed in a melting furnace without any problem. A smelting furnace is a fairly simple and inexpensive device consisting of a large cylindrical furnace that only needs to be able to tilt over part of a full circle around its longitudinal axis. This finding has the advantage that the raw solder can be produced by the method of the present invention, for example as temporary production campaigns, in the same smelting facility which, for example, in other campaigns also produces a copper metal phase of at least 70% by weight and usually 75 wt.% Cu, also known as "black copper", and / or in a smelting device which also recovers copper of even higher purity from such a copper concentrate. Optionally, a simple rinsing step can be provided between the campaigns, as further explained below. The inventors have also found that the method of the present invention is capable of accepting finely divided base materials without operational problems. Applicants have further found that the reducing agent in step b) and / or step k) may already be added together with the base stock portion added as part of step a) and / or step j). Applicants have also found that if additional energy is to be provided as part of step c) and / or step I), this may optionally be carried out together with the addition of the reducing agent from step b) and / or step k) , and thus possibly also together with the addition of the base material portion of step a) and / or step j). BE2018 / 5240 Applicants have therefore found that step b) and step c), as well as step k) and step I) can be combined, and thus that the reducing agent of step b) and / or k) and the energy source of step c) respectively and / or step I) can be added together. This combination of steps can be performed separately from step a) and / or j), respectively, or can be combined with step a) or step j), respectively. Applicants note that the options identified above for steps a) -d) also apply to the corresponding steps j) -m) introduced later in this document. Applicants have found that certain materials can act simultaneously as a reducing agent and as an energy source if they comprise at least one metal less noble than Sn and Pb. An eminently suitable example of such a material is ferrosilicon (FeSi), a material in which both elemental iron and elemental silicon are present. Iron and silicon are both less noble than Sn and Pb. The elemental iron is able to act as a reducing agent, able to convert SnO 2 and / or PbO to Sn and Pb metal respectively, while the iron is converted to FeO and / or Fe 2 O 3 , this oxide moving to the slag phase. The elemental silicon is able to convert SnO 2 and / or PbO to Sn and / or Pb, while the silicon itself is converted to SiO 2 , which also enters the slag phase. BRIEF DESCRIPTION OF THE DRAWINGS The Figure shows a flow chart of an embodiment of the method according to an embodiment of the present invention. DETAILED DESCRIPTION The present invention will be described in specific embodiments and with reference to certain illustrations in what follows; however, the invention is not limited thereto, but is BE2018 / 5240 only limited by the claims. The illustrations described are only schematic and are non-limiting. In the figures, the size of some elements may be enlarged for illustrative purposes and not drawn to scale. The dimensions and relative dimensions do not necessarily correspond to actual practical embodiments of the invention. Furthermore, the terms top, bottom, top, bottom, and the like, in the description and claims are used for descriptive purposes, and not necessarily to describe relative positions. The terms thus used are interchangeable in appropriate circumstances, and the embodiments of the invention described herein may function in orientations other than those described or illustrated here. The terms "comprising" and "including", as used herein and in the claims, are inclusive or non-inclusive, and do not exclude the presence of additional, unlisted elements, constituent components, process or process steps. Accordingly, the terms "comprising" and "including" include the more restrictive terms "consisting essentially of" and "consisting of". Unless otherwise noted, all values reported herein include the range up to and including the indicated endpoints, and the values of the components or components of the compositions are expressed in percent by weight or% by weight of each component in the composition. In addition, any compound used here can be discussed interchangeably with regard to its chemical formula, chemical name, abbreviation etc. In this document, amounts of metals and oxides, unless otherwise indicated, are expressed in accordance with current Pyrometallurgy practices. The presence of each metal is usually expressed in its total presence, regardless of whether the metal is present in its elemental form (oxidation state = 0) or in any chemically bound form, usually in a BE2018 / 5240 oxidized form (oxidation state> 0). For the metals that can be relatively easily reduced to their elemental shape, and which can appear as molten metal in the pyrometallurgical process, it is quite common to express their presence in terms of their elemental metal shape, even when the composition of a slag or scratch, where the majority of such metals may in fact be present in an oxidized and / or chemically bonded form. Therefore, in the base material of the method of the present invention and in the raw solder of the present invention, the content of Fe, Sn, Zn, Pb, Cu, Sb, Bi, As, Ni is indicated as elemental metals. Less precious metals are more difficult to reduce under nonferrous pyrometallurgical conditions and are most common in an oxidized form. These metals are usually expressed in terms of their most common oxide form. Therefore, if necessary, the content of Si, Ca, Al, Na is expressed as SiO 2 , CaO, Al 2 O 3 , Na 2 O, respectively. In the context of the present invention, the term "less precious metals than metal X" means those metals that are more likely to undergo oxidation in the conditions and in the specific environment of the context in which the phrase is used, for the benefit of their capacity to effect a reduction of the metal X. For example, the term "metals less noble than Sn and Pb" refers to metals which, in the circumstances and in the specific environment of the context where the term is used, are more inclined are oxidative and capable of reducing Sn and Pb. In the context of the present invention, "smelter", "melting", "melting" or similar derivations of "melting" mean a method that involves much more than just changing the aggregation state of a substance from solid to liquid. In a pyrometallurgical smelter step, several chemical processes also occur that convert certain chemical compounds into other chemical compounds. Important of those conversions can be oxidations BE2018 / 5240, with or without the formation of an oxide, or reductions, in which the oxidation state of some atoms change. In the context of the present invention, "scratch" or "scratches" means an often powdery or pasty substance that forms as a result of an operational step, and which separates from another liquid phase, usually under the influence of gravity, and usually floats to the surface. The scratch or scratches can therefore usually be mechanically scraped off or removed from the underlying liquid. In the context of the present invention, by "the solder", or also "the solder", is meant a metal composition which is rich in tin and / or lead, but which may also contain other metals. Solder typically has a relatively low melting temperature, which makes the composition suitable for forming a metal bond between two other metal parts, the so-called "soldering", upon heating to a relatively limited temperature. The metals of interest for this invention, in the typical conditions in a pyrometallurgical furnace in the processing of nonferrous metal, have affinities for oxygen, and tend to split between the metal and slag phases. The ranking of these metals from a lower to a higher affinity for oxygen, and thus from a relatively high affinity to a lower affinity for the metal phase, can be roughly represented as follows: Au> Ag »Bi / Cu> Ni> As> Sb > Pb> Sn »Fe> Zn> Si> Al> Mg> Ca. For the sake of convenience, this can be called a ranking of the metals from the noble to the less noble, but this qualification must be linked to the specific states and conditions of pyrometallurgical processes for non-ferrous metal, and may become unsuitable when transferred to other domains exported. The relative position of specific metals in this list can be influenced, among other things, by the presence or absence of other elements in the furnace, such as silicon. The equilibrium distribution of metal between metal and slag phase can also be influenced by adding BE2018 / 5240 oxygen and / or oxygen scavenging materials (or reducing agents) in the liquid bath in the oven. By adding oxygen, some of the metals in the metal phase will be converted to their oxidized form, after which this oxide will transition to the slag phase. The metal phase metals that have a high affinity for oxygen will be more likely to undergo this conversion and transition to the other phase. Thus, their equilibrium distribution between metal and slag phase may be more subject to change. The opposite can be achieved by adding oxygen scavenging materials. Suitable oxygen consumers can be, for example, carbon and / or hydrogen in any form, such as in organic materials, for example plastics, including polyvinyl chloride (PVC), wood, or other flammable substances, such as natural gas. Carbon and hydrogen can easily oxidize (“burn”) and convert to H 2 O and / or CO / CO 2 , components that easily leave the liquid bath and carry their oxygen content from the bath. But also metals such as Si, Fe, Al, Zn and / or Ca are suitable as reducing agents. Iron (Fe) and / or aluminum (Al) are particularly interesting because they are readily available. By oxidizing, these components will reduce some of the metals in the slag phase from their oxidized state to their metal state, and these metals will then move to the metal phase. Now, it is the slag phase metals that have a lower affinity for oxygen that will be more likely to undergo this reduction reaction and reverse the transition. In a smelting step, one of the objects is to reduce oxides of valuable non-ferrous metals entrained with the raw material to their corresponding reduced metals. In addition, the direction and speed of the reactions taking place in the melting step can be controlled by checking the nature of the atmosphere in the furnace. Alternatively, or additionally, BE2018 / 5240 oxygen supplying material or oxygen scavenging material can be added to the melting furnace. An extremely suitable oxygen scavenging material for such operations is iron metal, usually iron scrap being preferred. Under the typical operating conditions, the iron will react with hot oxides, silicates and the other compounds of metals with a lower affinity for oxygen than iron, to yield a melt containing the latter metals in elemental form. Typical reactions include: MeO + Fe -> FeO + Me + heat (MeO) x SiO 2 + x Fe -> (FeO) x SiO 2 + x Me + heat The temperature of the bath remains high due to the exothermic reaction heat and the combustion heat. The temperature can easily be kept in a range in which the slag remains liquid and lead and / or tin volatilization is limited. Each of the reduction reactions that take place in the melting furnace is reversible. Thus, the conversion achieved by each response is limited by the equilibria defined in relationships such as the following: [FeO] [Me] K1 = ......................... [MeO] [Fe] [(FeO) x SiO 2 ] [Me] x K2 = .............................. ....... [(MeO) x SiO 2 ] [Fe] x In the case where Me is copper, K1 and K2 are high at normal reaction temperatures and thus the reduction of copper compounds is practically complete. In the case of lead and tin, K1 and K2 are both relatively low, but the copper in the metal phase, if present in sufficient quantities, can extract metallic lead and tin from the slag reaction zone, thus causing the activities of these metals in the slag is reduced and the reduction of combined lead and tin is driven to completion. BE2018 / 5240 The vapor pressure of zinc is relatively high at the typical reaction temperature, and zinc, unlike lead and tin, is readily volatilized from the oven. Zinc vapors exiting the furnace are oxidized by air, which can for example be drawn between the mouth of the furnace and the hood and / or the exhaust pipe. The resulting zinc oxide dust is condensed and collected by conventional dust collection systems. In an embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises more than 50% by weight of total metal, preferably at least 51% by weight, more preferably at least 52% by weight %, even more preferably at least 53% by weight, preferably at least 54% by weight, more preferably at least 55% by weight, even more preferably at least 56% by weight, even more preferably at least 57 wt%, preferably at least 58 wt%, more preferably at least 59 wt%, and even more preferably at least 60 wt% total metal, preferably at least 65 wt%, more preferably at least 70% by weight, even more preferably at least 75% by weight. In an embodiment of the method of the present invention, the base material further comprises substances or components selected from O and S atoms, for example, when present in oxides and / or sulfides, any of the halogens, carbon and organic material. The base material includes a metallic portion, i.e. the amount of total metal in weight percent, and usually also a non-metallic portion representing the remainder of the base material. We have found that the remainder of the base material is preferably selected primarily from O and S atoms present in oxides and / or sulfides, any halogen, carbon, and / or organic material. Applicants prefer that the base material, in addition to the metals, mainly comprise O and S atoms, preferably when present in oxides and / or sulfides, carbon, or organic material, such as most plastics, including PVC, BE2018 / 5240 because the method can be easily adapted to deal with these additional substances or components, for example by providing suitable exhaust gas treatment installations. More preferably, the base material, in addition to the metals, contains oxygen, for example, as part of oxides, carbon and / or organic material, because of the ease with which the process can handle it. Most preferably, applicants prefer oxygen in the form of metal oxides, since other components may cause emissions problems, for example, as SO 2 or SO 3 , as CO or CO 2 , dioxins, etc., and this form of oxygen as metal oxides therefore simplify the treatment of the furnace exhaust gases. In an embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises more than 2 wt% tin, preferably at least 4 wt%, more preferably at least 6 wt% even more preferably at least 8 wt%, preferably at least 10 wt%, more preferably at least 12 wt%, even more preferably at least 14 wt%, even more preferably at least 16 wt% % tin, preferably at least 18% by weight, more preferably at least 20% by weight, even more preferably at least 22% by weight, even more preferably at least 24% by weight tin. We have found that a higher amount of tin in the base material lowers the melting point of the base material, with the advantage that the process of the present invention becomes practicable over a wider temperature range. We have also found that there is more demand for the high purity tin metal which can ultimately be recovered from the raw solder obtainable by the method of the present invention, compared to the high purity lead metal. Thus, a higher tin content in the process streams of the present invention increases the economic interest in the raw solder obtainable by the process of the present invention as a further base material for recovering high purity tin metal. BE2018 / 5240 In an embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises less than 71 wt% tin, preferably at most 69 wt%, more preferably at most 65 wt% even more preferably at most 62 wt%, even more preferably at most 59 wt%, preferably at most 56 wt%, more preferably at most 53 wt%, even more preferably at most 50 wt% %, even more preferably less than 50 wt%, preferably at most 48 wt%, more preferably at most 46 wt%, even more preferably at most 45 wt%, preferably at most 44 wt% %, more preferably at most 43 wt%, even more preferably at most 42.5 wt%, even more preferably at most 42 wt% tin, preferably at most 41 wt%, more preferably at most 40 wt%, preferably at most 38 wt%, more preferably at most 36 wt%, even more preferably at most 34 wt%, at preferably at most 32 wt%, more preferably at most 30 wt%, even more preferably at most 28 wt% tin. We have found that a lower amount of tin in the base material is beneficial to downstream separation processes. We also found that a lower tin content of the base material has the advantage of lowering the solubility of copper in the base material, leading to a lower copper content in the final high performance products, such as tin and lead, after further downstream processing, for example by vacuum distillation, which increases the economic value of these high performance products and / or alleviates the burden of removing the residual traces of copper in an additional copper removal process step downstream. In an embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises more than 1.00 wt% copper, preferably at least 1.02 wt%, more preferably at least 1.05 wt%, preferably at least 1.07 wt%, more preferably at least 1.10 wt%, even more preferably at least 1.12 wt%, even more BE2018 / 5240 preferably at least 1.15 wt% copper, preferably at least 1.17 wt%, more preferably at least 1.19 wt%, even more preferably at least 1.20 wt%, preferably at least 1.30 wt%, more preferably at least 1.40 wt%, even more preferably at least 1.60 wt%, more preferably at least 1.80 wt%, with still more preferably at least 1.90 wt% copper. We have found that the amounts of copper as prescribed in accordance with the present invention can be left in the raw solder without compromising the usefulness of the solder after updating as further base material for a vacuum distillation step, and thus without affecting the effect that achieved by the present invention is significantly reduced or nullified, ie without increasing the risk that a vacuum distillation step performed on the updated solder would no longer be able to operate in continuous mode for long periods of time without problems to obtain from copper-containing metal-metal compounds that hinder the distillation operations. We have found that the identified problems can be reduced to a practical and economically acceptable level if the small amounts of copper, as directed, remain in the raw solder of the present invention, as prescribed, when it is used after processing as the base material for a vacuum distillation step to separate at least a part of the lead in the soldering current. In an embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises less than 10 wt% copper, preferably at most 9 wt%, more preferably at most 8 wt% , preferably at most 7 wt%, more preferably at most 6 wt%, and even more preferably at most 5.7 wt%, preferably at most 5.5 wt%, more preferably at most 5 wt%, even more preferably at most 4.5 wt%, preferably at most 4 wt%, more preferably BE2018 / 5240 at most 3.5 wt%, preferably at most 3 wt%, more preferably at most 2.5 wt%, even more preferably at most 2 wt% copper. We have found that the lower the concentration of copper in the base material, the lower the risk of metal-metal bond formation when the raw solder obtainable by the method of the present invention is subjected to vacuum distillation after updating. . We have also found that the lower the presence of copper in the base material, the lower the concentration of copper in the product streams from the downstream vacuum distillation. This alleviates the burden in the further removal of copper from these streams on their path to become high quality products, especially in terms of consumption of chemicals and in terms of amounts of by-products formed. In one embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises more than 0.02 wt% antimony, preferably at least 0.05 wt%, more preferably at least 0.08 wt%, preferably at least 0.10 wt%, more preferably at least 0.12 wt%, even more preferably at least 0.14 wt%, even more preferably at least 0 , 16 wt% antimony, preferably at least 0.18 wt%, more preferably at least 0.20 wt%, even more preferably at least 0.22 wt%, preferably at least 0.24 wt.%, more preferably at least 0.26 wt.%, even more preferably at least 0.28 wt.%, preferably at least 0.30 wt.%, more preferably at least 0.32 wt. %, even more preferably at least 0.34 wt%, even more preferably at least 0.36 wt% antimony. We have found that the base material may contain measurable, and even significant, amounts of antimony, within the stated limits, without this presence of antimony causing significant drawbacks to any downstream vacuum distillation. We have found that this provides additional freedom of action for the base material. Thanks to this, allow an amount of antimony in the raw solder which is available through BE2018 / 5240 the method of the present invention, the method of the present invention is able to accept a base material in which antimony is present. Antimony can be present in various primary and secondary base materials for non-ferrous metals, as well as many end-of-life materials. For example, antimony may be present in lead, which has been used for plumbing since the Roman era. These materials can now become available as breakdown materials, often in combination with copper for pipes and other purposes, and with tin and lead for the solder joints. By admitting an amount of antimony in the raw solder obtainable by the method of the present invention, the method of the present invention is enabled to accept such mixed materials at the end of their life in the base material. We have found that significant concentrations of antimony are allowed in the raw solder obtainable by the method of the present invention without this creating significant difficulties for the downstream methods. In an embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises less than 5 wt% antimony, preferably at most 4 wt%, more preferably at most 3 wt% even more preferably at most 2% by weight, even more preferably at most 1.5 wt%, preferably at most 1.00 wt% of antimony, more preferably at most 0.95 wt%, even more preferably at most 0.9 wt%, preferably at most 0, 87 wt%, more preferably at most 0.85 wt%, even more preferably at most 0.8 wt%, even more preferably at most 0.75 wt%, preferably at most 0.7 wt%, more preferably at most 0.65 wt%, even more preferably at most 0.6 wt%, preferably at most 0.5 wt%, more preferably at most 0.4 wt. %, even more preferably at most 0.35% by weight of antimony. We have found that antimony can be allowed into the base material, within specific limits, BE2018 / 5240 without causing problems when the raw solder obtainable by the method of the present invention is updated and used as the base material for downstream vacuum distillation. We found that it is important to keep the amount of antimony below the indicated upper limit because antimony can also at least partially evaporate under the distillation conditions. If the antimony content is higher, the amount of antimony exiting the distillation step with the lead lead product can become significant. To obtain the higher purity top quality lead product in accordance with desired industry standards, this amount of antimony should be removed from this lead stream in the conventional cleaning steps downstream of the distillation step. An amount of antimony higher than the indicated limit increases the burden of these downstream cleaning steps and increases the amount of by-product streams containing the antimony. Since these by-product streams can also contain significant amounts of lead, this lead in the by-products does not end up in the top quality lead product and at least reduces the effectiveness of the entire operation. In an embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises more than 0.0004 wt% bismuth, preferably at least 0.0005 wt%, more preferably at least 0.0006 wt%, preferably at least 0.0007 wt%, more preferably at least 0.0008 wt%, even more preferably at least 0.0009 wt%, even more preferably at least 0.0010 wt% bismuth, preferably at least 0.002 wt%, preferably at least 0.003 wt%, more preferably at least 0.004 wt%, even more preferably at least 0.005 wt%, preferably at least at least 0.0075 wt%, more preferably at least 0.01 wt%, even more preferably at least 0.0125 wt%, even more preferably at least 0.015 wt%, preferably at least 0.020 wt% bismuth. In one embodiment of the method of the present invention, the base material, relative to the BE2018 / 5240 total dry weight of the base material, less than 1.0 wt% bismuth, preferably at most 0.8 wt%, preferably at most 0.6 wt%, more preferably at most 0.4 wt% .%, even more preferably at most 0.2 wt%, and even more preferably at most 0.1 wt% bismuth, preferably at most 0.08 wt%, more preferably at most 0, 06 wt%, even more preferably at most 0.05 wt%, preferably at most 0.04 wt%, more preferably at most 0.03 wt%, even more preferably at most 0.025 wt. % bismuth. We have found that bismuth can be admitted into the base material, within specific limits. We found that bismuth can be relatively volatile under the conditions of the vacuum distillation step. Part of the bismuth can therefore end up in the high-quality products, from which it must then be removed to obtain a high-quality product that meets the desired product specifications. This downstream removal of contaminants consumes chemicals and creates a stream of by-product that also contains a measure of valuable high-quality product. Even if successfully recycled, these by-product streams represent process inefficiency that is advantageously reduced. It is therefore more advantageous to limit the amount of bismuth in the base material. We have further found that the risk of forming potentially interfering metal-metal compounds is reduced by controlling the presence of the above-mentioned compounds, tin, copper, antimony and bismuth, in the base material between the levels mentioned. In an embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises less than 1.0 wt% arsenic, preferably at most 0.8 wt%, more preferably at most 0.6 wt%, preferably at most 0.4 wt%, more preferably at most 0.3 wt%, even more preferably at most 0.20 wt%, and even more preferably at highest 0.185 wt% arsenic, preferably at most BE2018 / 5240 0.18 wt%, more preferably at most 0.175 wt%, even more preferably at most 0.170 wt%, preferably at most 0.15 wt%, more preferably at most 0.13 wt% , even more preferably at the most 0.11 wt% arsenic. We prefer to keep the amounts of arsenic in the base material within limits. This eases the burden of removing arsenic downstream from any product streams from a possible vacuum distillation step. In these downstream removal steps, chemicals are used and by-product streams are formed which inevitably also contain certain amounts of valuable metals, such as lead and / or tin. Even if recycled successfully, these by-product streams represent global process inefficiencies, and it is advantageous to reduce their volume. Recycling can also cause problems caused by the chemicals in these by-product streams, such as a corrosive effect on refractories used in the equipment and in contact with the hot liquid streams. In one embodiment of the method of the present invention, the base material comprises less than 2.0 wt% nickel, preferably at most 1.7 wt%, more preferably at most 1, relative to the total dry weight of the base material , 5 wt%, even more preferably at most 1.2 wt%, even more preferably at most 1.0 wt%, preferably at most 0.8 wt%, more preferably at most 0 , 6 wt%, preferably at most 0.50 wt%, more preferably at most 0.45 wt%, even more preferably at most 0.40 wt%, and even more preferably at most 0 .35 wt.% Nickel, preferably at most 0.30 wt.%, More preferably at most 0.29 wt.%, Even more preferably at most 0.28 wt.%, Preferably at most 0.26 % by weight, more preferably at most 0.24% by weight, even more preferably at most 0.22% by weight, preferably at most 0.20% by weight, more preferably at most 0.18% by weight. %, even more preferably at most 0.16% by weight, b Preferably at most 0.14 wt%, more preferably at most 0.12 wt% nickel. BE2018 / 5240 We have found that the risk of forming potentially interfering metal-metal compounds is reduced by keeping the presence of the above-mentioned compounds, arsenic and nickel, in the base material below lower levels. Nickel is a metal that is present in many raw materials that are available for the recovery of non-ferrous metals, especially in secondary raw materials, and especially in end-of-life materials. It is therefore important in the recovery of non-ferrous metals that the process is able to deal with the presence of nickel. In addition, the pyrometallurgical processes for the recovery of non-ferrous metals often consume significant amounts of iron as a process chemical. It is advantageous to be able to use secondary ferrous materials for this purpose. In addition to large amounts of iron, these materials can also contain smaller amounts of nickel. It is advantageous to also be able to handle a certain amount of these types of chemical process substances. We have further found that it is preferable to decrease the nickel content in the base material for the process of the present invention, rather than removing larger amounts of nickel downstream. Such downstream nickel removal is usually performed in conjunction with the removal of arsenic (As) and / or antimony (Sb), and carries the risk of producing highly toxic gases arsine (AsH 3 ) and / or stibine. (SbH 3 ). The removal of nickel within the specified limits therefore also reduces the risk of toxic gases being released downstream, and is therefore also a measure of safety and industrial hygiene. In an embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises at least 8 wt% lead, preferably at least 10 wt%, more preferably at least 15 wt% even more preferably at least 20 wt%, preferably at least 22 wt%, more preferably at least 24 wt%, even more preferably at least 26 wt%, even more preferably at least 30 wt % lead, preferably at least BE2018 / 5240 at least 33 wt%, more preferably at least 36 wt%, even more preferably at least 40 wt% lead. In an embodiment of the method of the present invention, the base material, relative to the total dry weight of the base material, comprises at most 80% by weight of lead, preferably less than 79% by weight, more preferably at most 75% by weight even more preferably at most 70 wt%, even more preferably at most 69 wt%, and even more preferably at most 68 wt% lead, preferably at most 65 wt%, more preferably at at most 60 wt%, preferably at most 55 wt%, more preferably at most 50 wt%, even more preferably at most 45 wt%, preferably at most 42 wt%, more preferably at most 41 wt%, preferably at most 40 wt%, more preferably at most 35 wt%, even more preferably at most 30 wt% lead. Applicants prefer to work with the lead content within the prescribed limits, because on the one hand this offers the advantage of a high-density solder which makes it easier to separate the molten solder from the slag phase by gravity, and on the other hand significantly a lot of space for tin metal, which is significantly more valuable than lead, which is advantageous for the added economic value of the method according to the present invention. In an embodiment of the method of the present invention, the base material is characterized by a lead / tin (Pb / Sn) weight ratio of greater than 0.50, preferably at least 0.52, more preferably at least 0.53 , preferably at least 0.54, more preferably at least 0.55, even more preferably at least 0.56, even more preferably at least 0.57, preferably at least 0.60, more preferably at least at least 0.65, even more preferably at least 0.70, preferably at least 0.80, more preferably at least 0.90. In one embodiment of the method of the present invention, the base material is characterized by a lead / tin ratio less than 4.0, preferably at most 3.5, more preferably at most 3.2, even more preferred at most 3.1, at BE2018 / 5240 preferably at most 3.0, more preferably at most 2.9, and even more preferably at most 2.8, preferably at most 2.5, more preferably at most 2.2, with even more preferably at most 2.0, preferably at most 1.8, more preferably at most 1.6. The inventors have found that the remaining slag contains lower amounts of valuable tin when the lead / tin ratio is between the stated levels. When the lead / tin ratio of the base material is too low, i.e. less than 0.5, more lead-containing materials are preferably added to the base material until a ratio of at least 0.5 is obtained. The inventors have found that when the base material contains more lead, the relative amount of tin in the raw solder relative to the amount of tin in the base material is also higher. The inventors have found that by providing more lead along with the tin, the recovery of tin in the process is improved, and less of the available tin ends up in the slag. The inventors have found that keeping the lead / tin ratio within the prescribed limits improves the various gravity separation steps in the global process. As explained above, the method of the present invention includes step a) and / or step j) of applying a liquid bath of a metal phase and / or a slag in an oven by heating and melting at least a portion of the base material said base material preferably being retained by a screen having a screen opening equal to or less than 3.0 mm. In an embodiment of the method of the present invention, step a) and / or step j) further comprises adding lead in the furnace, preferably in the form of lead metal, lead scrap or lead compounds, preferably lead oxides. The inventors have found that the addition of lead dilutes the Sn, both in the metal phase and in the slag, resulting in the recovery of the Sn, which is available in the oven, in the raw BE2018 / 5240 solder is improved. The inventors have further found that the downstream processing of the raw solder is improved by a higher presence of Pb. The oven used in step a) and / or step j) of the process of the present invention may be any oven known in the Pyrometallurgy art, such as an Isasmelt oven, an Ausmelt oven, a top-blown rotary converter (TBRC) or a smelting furnace. In one embodiment, the oven used in step a) and / or step j) of the method of the present invention is a melting furnace. In a smelting furnace, the metals are melted, and organic matter and other flammable materials are removed by combustion. The smelting furnace is therefore able to absorb much lower quality raw materials, which are usually available in larger quantities at more economically attractive conditions. The process of the present invention, carried out in a smelting furnace, can therefore accept raw materials which may not be able to accept alternative methods known in the art, or which can only accept in very limited quantities, and which can thus be readily available at more economically attractive conditions . Applicants have found that a smelting furnace step is extremely suitable, and even preferable, for carrying out the method of the present invention. A smelting furnace step offers the advantage of being simple in operation and equipment, and therefore economically advantageous. In addition, a smelting furnace step brings the additional advantage of being tolerant of raw material quality. A smelting furnace step is able to accept raw materials that are highly diluted and / or contaminated with a wide variety of components, including organic materials, rubbers, plastics, paint, wood and the like. Because this mixed BE2018 / 5240 and / or contaminated raw materials hardly have any other end use, they can be supplied under economically very attractive conditions. The ability to process these raw materials and refine the precious metals contained therein is therefore important to the user of the method of the present invention. The inventors have found that the method of the present invention is preferably performed in a melting furnace because the method of the present invention is then able to easily accept base materials in finely divided form, without any operational problems. An additional advantage of using a smelting furnace is that a smelting furnace is a fairly simple and inexpensive device, which usually consists of a large cylindrical furnace which only needs to be able to tilt about a full circle around its axis. In one embodiment of the method of the present invention, the part or portion of the base material used in step a) and / or step j) comprises divided solid material, and comprises at most 5% by weight of particles passing through a screen with a 2.0 mm sieve opening, also known as a Mesh 9 sieve, preferably less than 5 wt%, more preferably at most 4 wt%, even more preferably at most 3 wt%, even more preferred at most 2 wt% and even more preferably at most 1.0 wt%. In an embodiment of the method according to the present invention, the part of the base material used in step a) and / or step j) comprises at most 5% by weight of particles passing through a sieve with a sieve opening of 2.38 mm, also known as a Mesh 8 sieve, preferably a 2.83 mm sieve opening, also known as a Mesh 7 sieve, more preferably a 3.36 mm sieve opening, also known as a Mesh 6 sieve, and preferably less than 5 wt%, more preferably at most 4 wt%, even more preferably at most 3 wt%, even more preferably at most 2 wt%, and even more preferably at most 1 wt%. BE2018 / 5240 We have observed that many of the secondary base materials for non-ferrous metal recovery are mainly available in finely divided form, or contain significant amounts of small particles. The inventors have found that it is advantageous to limit the portion of the base material used in step a) and / or step j) in terms of the content of finely divided material. This can be accomplished, for example, by sieving at least a portion of the base material before it is used in step a) and / or step j), and using only the portion retained by the screen as indicated. Another suitable possibility is to keep the raw materials rich in finely divided material separate from raw materials that have a low content of finely divided material or no finely divided material, and use only the latter to be introduced in step a) and / or step j) of the method of the present invention. The advantage of this feature is that it reduces the risk of many of the small particles in the raw material being blown out of the furnace in which the liquid molten metal bath is built up as part of step a) and / or step j), and would therefore not become part of the liquid bath. In particular, when the base material is heated and / or melted by burning a liquid or gaseous fuel with air and / or oxygen, the step a) and / or step j) may be characterized by a large volume of exhaust gases, and the gas velocities in the oven and in the flue gas outlet pipe are high. High speed gas is able to easily carry small solid particles, and the smaller they are, the easier they are carried. Solid particles entrained with the furnace exhaust gases no longer participate in the process step. They place an additional burden on the exhaust gas treatment equipment as they must be removed before the exhaust gases may be released into the atmosphere. When recovered, these solid particles or dust should preferably be reprocessed rather than dumped as waste. BE2018 / 5240 The inventors have found that increasing the mesh size or sieve openings of the sieves to retain the base material for stapa) and / or stepj) has the advantage that stapa) and / or stepj) can be performed at higher gas speeds without increase the risk of dust entrained from the oven into the exhaust fumes. Higher gas velocities mean that the energy input into the furnace can be increased, and building the liquid bath in step a) and / or step j) can be less time consuming. In an embodiment of the method of the present invention, the pieces used as the base material have at least two dimensions smaller than 0.5 m. This has the advantage that all pieces are easily passed through a typical furnace feed opening to carry out the method of the present invention, which is a square with a size of 0.5 x 0.5 m. The inventors have found that the use of a base material retained by a screen with a prescribed screen opening also avoids any industrial hygiene problems associated with base material dust in the working environment and atmosphere. Many of the base materials that contain valuable Sn and / or Pb are available in a finely divided form. For example, emissions in the form of dust collected in waste gas filter units, or emissions from drying units where the oxidic metal raw materials are mixed, dried and sieved, often contain significant amounts of Sn and / or Pb. The finely divided base materials are preferably not supplied in step a) and / or step j) of the process of the present invention, for the reasons stated above. However, the inventors have found that the method of the present invention is able to accept finely divided base materials without operational problems, for example when the finely divided base materials are injected into the liquid bath contained in the oven during operation, preferably when a suitable one BE2018 / 5240 and a sufficiently large amount of liquid bath is present, more preferably when the liquid bath comprises a layer of liquid slag, such as when a liquid bath is built up on the basis of the larger base material which is preferred for step a) and / or step j) . In a further embodiment, the method of the present invention further comprises the step of injecting, into the liquid bath formed in step a) and / or step j), a finely divided portion of the base material, the finely divided portion of the base material has an average particle size of at most 10 mm, preferably at most 8 mm, more preferably at most 6 mm, even more preferably at most 5 mm, even more preferably at most 4 mm, preferably at most 3 mm, more preferably an average particle size smaller than the sieve opening prescribed in the description of the preferred base material portion for step a) and / or step j). The finely divided portion of the base material can be injected into the molten metal phase, if any, and / or into the molten metal oxide slag phase, if any. Preferably, the finely divided portion of the base material is injected below the liquid level of the liquid bath formed in the oven after step a) and / or step j) such that the risk of entraining the small particles with the flow of exhaust gas from the oven is lowered. This has the advantage that the method is able to handle base materials that are available in a finely divided form. Many sources of suitable finely divided base materials exist. Because these are less acceptable in alternative applications, the ability of the method to handle these base materials represents a higher economic upgrade. In one embodiment, the finely divided portion of the base material is injected into the liquid slag phase and above the metal phase of the liquid bath. This has the advantage that the material is easily absorbed in the liquid bath, melts quickly and reacts to form the desired components of reduced metal and oxidized metal, which can then easily enter the BE2018 / 5240 respective liquid phases, depending on their density. This feature has the additional advantage that the injection of the finely divided portion of the base material involves only minor additional disturbance to the formation of the two phases in the liquid bath, ie the lower phase of molten metal and the upper phase of liquid snail. The inventors have found that injecting the finely divided portion of the base material or material into the liquid slag phase improves the absorption of the finely divided particles of base material into the slag by increasing its residence time in the liquid phase. The inventors have further found that it is preferable to ensure that a suitable and sufficiently large amount of slag is present before the finely divided base material is injected. Applicants prefer not to inject the finely divided portion of the base material or material into the bath until a continuous supernatant slag phase is present in the liquid bath. This has the advantage of greatly reducing the risk that a significant portion of the finely divided portion of the base material would not remain in the liquid bath and leave the oven along with the exhaust gases. Typically, an appropriate amount of slag phase for a suitable injection of finely divided basestock is 0.6 tons, preferably 0.65 tons, more preferably 0.7 tons, per ton of metal in the liquid bath. In an embodiment of the method of the present invention, the finely divided portion of the base material has an average particle size of at most 3.36 mm, preferably at most 2.83 mm, more preferably at most 2.38 mm, with still more preferably at most 2.00 mm, even more preferably at most 1.68 mm, preferably at most 1.50 mm, more preferably at most 1.30 mm, even more preferably at most 1.20 mm even more preferably at most 1.10 mm, even more preferably at most 1.00 mm. Applicants have found that the smaller the finely divided particles of base material, the fewer possible alternatives BE2018 / 5240 applications exist for this material, and therefore the higher the possible upgrading that can be provided by the method of the present invention. Applicants have further found that the smaller the finely divided particles of base material, the more reactive these particles are, and the faster the same amount of base material can be processed in the process of the present invention. Injection of the finely divided portion of the base material can be performed by suitable injection techniques known to those skilled in the art, for example, by injection using compressed air. In one embodiment, the molten metal liquid bath obtained in step a) and / or step j) of the method of the present invention is kept at a temperature of at least 975 ° C, preferably at least 1000 ° C, with more preferably at least 1050 ° C, even more preferably at least 1075 ° C, even more preferably at least 1100 ° C, more preferably at least 1125 ° C, even more preferably at least 1150 ° C. Applicants have found that this lower limit, as indicated, has the advantage that the slag in the furnace remains liquid and maintains a viscosity that allows the slag to be poured smoothly from the furnace without significant entrainment of portions of the underlying molten metal phase. In one embodiment, the molten metal liquid bath obtained in step a) and / or step j) of the method of the present invention is kept at a temperature of at most 1360 ° C, preferably at most 1340 ° C, with more preferably at most 1320 ° C, even more preferably at most 1300 ° C, even more preferably at most 1280 ° C, preferably at most 1240 ° C, even more preferably at most 1220 ° C. Applicants have found that the upper limit, as indicated, has the advantage of reduced wear and / or damage to the furnace equipment in contact with the hot liquid bath. As explained above, the method of the present invention includes step b) and / or step k) wherein BE2018 / 5240 at least one reducing agent is introduced into the liquid bath to reduce at least a portion of the oxidized valent form of tin and / or lead to tin and / or lead metal, respectively. As mentioned elsewhere, the oxidized valent form of tin and / or lead is preferably tin and / or lead oxide. In a preferred embodiment, the at least one reducing agent is a metallic material containing at most 25% by weight of copper. Preferred reducing agents for step b) and / or step k) are low Cu metallic materials. In the context of the present invention, the term "low Cu metallic materials" means metallic materials containing less than 25 wt% copper, preferably metallic Sn and SnZn materials containing less than 25 wt% copper. The term "metallic materials" means materials whose total metal content, relative to the total dry weight of the material, is prescribed in an identical manner to the total metal content of the base material of the process of the present invention. The reducing agent used in step b) and / or step k) of the process of the present invention is added to reduce any Sn and / or Pb oxides to their metals, and is usually selected from carbon, metals which less noble than Sn and Pb, and secondary base materials rich in elemental Fe, Al and / or Si, preferably secondary base materials rich in Fe, Al and / or Si metal. Typically, any silicon metal present in the preferred reducing agent is secondary in quantity or accidental, since materials rich in silicon metal are quite scarce and readily find an alternative and higher value application compared to their use as a reducing agent in the method of the present invention. We have identified oxides for basic materials containing oxidized metal components such as Cu, Sn, Pb and / or Ni BE2018 / 5240 that many of these metal oxide components can be easily reduced to release their respective free metal forms, by introducing into the furnace other, preferably secondary base materials rich in elemental Fe, Al and / or Si, such as ferrosilicon ( FeSi). Such Fe, Al and / or Si metals may be contaminated with additional Cu or Sn, and thus may be streams with a limited number of processing options, such as some of the waste streams from the manufacture of silicon for electronic final applications. The Fe, Al and / or Si metal is able to react with the oxides of the more noble elements Cu, Sn, Pb, Ni. As a result of this reaction, the less noble metals Fe, Al, Si will be oxidized, their oxides tending to become part of the slag, and easy to separate from the reduced metal bath. We have further found that the added reducing agent, which is usually solid, usually floats at the interface between the liquid metal phase and the slag, exactly in the reaction zone where it can perform optimally as a reducing agent. These oxidation / reduction reactions can generate enough heat to melt the additional raw material and to maintain the temperature in the oven. The inventors have found that elemental Al and Si provide considerably more energy than Fe, but in too high Al and Si concentrations the viscosity of the slag can increase. The inventors have further found that the total amount and the overall composition of the added reducing agent are preferably adjusted according to the amount of the target metals present in the bath in the form of their oxides and which are to be reduced, and also that the addition is preferably carried out gradually and / or at intervals, such that the reaction proceeds in a controlled manner to maintain stable operation. In one embodiment of the method of the present invention, the at least one reducing agent comprises secondary base materials rich in Fe, such as materials having at least 20 wt% Fe, preferably at least 30 wt% Fe, more preferably BE2018 / 5240 at least 40 wt% Fe, even more preferably at least 45 wt% Fe. Preferably, these secondary base materials are not only Fe-rich but additionally contain an amount of Sn, such as at least 3% Sn, preferably at least 5 wt% Sn, more preferably at least 10 wt% Sn, and contain moreover, relatively little Cu, such as at most 5 wt% Cu, preferably at most 3 wt% Cu, even more preferably at most 1.5 wt% Cu. Suitable reducing agents in this category can be, for example, FeSn granulates, which are available in various degrees of purity, and are often referred to as "hardhead", a term quite common in metallurgy. Conventionally, carbon has often been used as the reducing agent. However, the inventors have found that carbon can form a foamy slag which can cause the furnace to overflow. In addition, the CO 2 generated in the reduction reaction, which escapes from the furnace as hot gas, represents a significant loss of heat. The inventors have further found that in the process of the present invention, the reduction reaction of Sn and / or Pb of their oxides to metals, due to the addition of a reducing agent in step b) and / or step k), at least in part can be accomplished by introducing secondary base materials rich in Fe, which preferably contain an amount of Sn, but little Cu, without forming a foamy slag or leading to a loss of heat. The oxides of the more noble metals in the slag, such as Sn and Pb, are reduced by adding Fe metal, converting the Fe metal into an oxidized form that travels into the supernatant slag, and the more noble metals such as Sn and Pb enter the heavier metal phase below. The inventors have further found that, to improve the kinetics of the reaction, the Fe metal supplied preferably has a large specific surface area. Therefore, fine scrap metal plates are preferably used, for example Fe / Sn waste material such as industrial production waste producing metal cans. Rejected materials from the metal can industry and / or from metal cans after their useful life BE2018 / 5240 has little to no other useful applications and poses a problem if they are thrown away as landfill waste. In one embodiment, the at least one reducing agent comprises metallic sand, such as "foundry sand". The inventors have found that such metallic sand or foundry sand is very suitable as a reducing agent in step b) and / or step k) of the method of the present invention. Foundry sand is a waste stream from foundries. Clean sand, which is usually treated with a small amount of organic binder, is used to form a mold, into which the red-hot and liquid iron or steel is then poured. The organic binder largely burns up during casting. After cooling, the sand is fairly smooth and the cast metal object can be easily released by removing the sand. Only part of this sand can be reused, because it has become too heavily contaminated with metal during the production process. A significant part should therefore be removed. This contaminated sand is called foundry sand. Foundry sand has little to no useful or valuable application and therefore often ends up in landfills. This dumping of sand represents an environmental burden that is becoming increasingly problematic for the foundry operator. We have found that the foundry sand is an interesting reducing agent in step b) and / or step k) of the method of the present invention, due to its smooth availability from a large number of sources and the lack of high-quality alternative options for its processing . As explained above, the method of the present invention includes the optional step c) and / or step I), wherein at least one energy source is introduced into the furnace comprising at least one metal less noble than Sn and Pb, and wherein the at least one metal in the energy source is oxidized by injecting air and / or oxygen into the furnace. In one embodiment, step c) and / or step I) is present in the method of the present invention. BE2018 / 5240 The energy source used in step c) and / or step I) of the method of the present invention is preferably selected from the group consisting of metals less noble than Sn and Pb, in particular selected from elemental Fe, Si, Mg, Zn, Al, Ca and Na, alternatively also called the respective "metal", and combinations thereof. In an embodiment of the method of the present invention wherein step c) and / or step I) is present, air and / or oxygen is injected into the liquid bath, usually in the form of enriched air, more preferably as purified oxygen gas. We have found that a metal less noble than Sn and Pb is able to provide additional energy by releasing the heat of oxidation, while at the same time reducing Sn and / or Pb oxides to their elemental metal form. In addition, additional energy can be generated by injecting an appropriate form of oxygen gas into the liquid bath. The inventors have found that the oxygen gas is preferably injected below the liquid level in the oven, i.e. directly into the liquid bath. This has the advantage of a lower risk of losing some of the oxygen in the exhaust gases, and thus improves the effectiveness of the injection of the oxygen gas, thereby improving the energetic efficiency of the process. The inventors have further found that an injection of oxygen gas, optionally in combination or in mixture with natural gas, provides an independent and economical way of controlling and independently adjusting the total energy input to the furnace by controlling the flow of oxygen . Without oxygen input, pure or diluted, all energy input would have to be provided by the oxidation of metals added to the furnace. The energy input rate would then not be easily controllable, posing a risk of uncontrollable temperature rise. Maintaining an injection of oxygen gas to satisfy part of the Therefore, BE2018 / 5240 furnace energy requirements improves controllability of the furnace energy input rate, and reduces the risk of uncontrollable temperature excesses with potentially disastrous consequences. As explained above, the method of the present invention includes step d) and / or step m) in which the raw solder is separated from the slag. It should be understood that the separation can be accomplished by any suitable method known to those skilled in the art. In an embodiment of the method of the present invention, in step d) and / or step m), removing the raw solder and / or the slag from the oven is performed by the raw solder and / or the slag as a liquid from the drain the oven. The inventors have found that when the furnace is a smelting furnace, the raw solder can be drained during and / or at the end of the batch or campaign by tilting the melting furnace in one direction, passing the raw solder through a tap hole in the the wall of the melting furnace to flow into a suitable container. In an embodiment of the method of the present invention in which in step d) and / or step m) the raw solder is tapped from the oven as a liquid, the method further comprises the step of cooling / solidifying the tapped raw solder by contacting the raw solder with water to obtain crude solder granules. Applicants have found that the granular raw solder is easier to manipulate and to transport over long distances, such as when the raw solder is upgraded in a separate facility which may be located a great distance from the production site. The inventors have further found that, when the furnace is a smelting furnace, at the end of a production batch the slag can be poured into a pan through the loading opening of the smelting furnace, by tilting the melting furnace sideways, and then BE2018 / 5240 are cooled / solidified in direct contact with water, usually forming granules or a granulate product. The direct contact with water provides a quick quench, making the solder take the form of solder granules that are easy to manipulate. We have found that fast quenching is more advantageous compared to slow solidification because it is much faster, requires less work surface and is easier to manipulate the product. We have further found that it is advantageous to use an amount of water sufficient to transport the slag granulates to the granulation well for precipitation, and to at least partially recycle the water. The solder granules can then be removed from the granulation well by a tap or a shovel. The solder granules can be sold or upgraded. In one embodiment, the method of the present invention further comprises the step of recovering valuable metals from the slag from step d) and / or step m). Applicants have found that the slag from step d) and / or step m) contains sufficient amounts of tin and / or lead, and usually also of other valuable metals, such as copper or zinc, to justify their recovery. The slag is also too rich in leachable metals, such that dumping the slag would require complicated precautions to avoid possible soil and / or groundwater pollution problems. The recovery of valuable metals from the slag can be achieved by feeding the slag from step d) and / or step m) into a pyrometallurgical process for producing a non-ferrous metal, such as copper, zinc or nickel, where the tin and / or the lead in the slag is preferably recovered into a by-product of non-ferrous metal production, said by-product being introduced back into the process of the present invention, in step a) or downstream thereof. For example, the slag from step d) and / or step m) can be recycled during a copper production campaign, preferably in the same furnace, especially when the slag granulates contain significant amounts of useful metals such as Pb and Sn. BE2018 / 5240 In one embodiment, step d) and / or step m) of the method of the present invention further comprises before separating the slag from the crude solder and before removing at least a portion of the slag in step d) and / or step m), adding to the furnace an amount of inert particulate solid material, preferably sand (consisting mainly of SiO 2 ) or spent slag on top of the slag, usually as a shielding material. The inventors have found that the amount of inert particulate solid material, usually sand or spent slag, should be chosen to be sufficient for building a solid layer on top of the liquid level at the furnace outlet, ie sufficient to act as shielding material. The inert particulate solid material is preferably spread on top of the liquid level. The inert solid material is also preferably added only shortly before the slag is removed from the oven by "pouring out" the slag phase. This has the advantage that less of the solid material gets the time and temperature exposure it takes to melt and transition into the liquid bath, such that more of the solid material remains available to form the "screen" that , when the slag is poured off, retains other solid material that may float on top of the fluid bath. Smoothly acceptable particulate materials are materials that do not disturb the slag / metal equilibrium, nor do they significantly affect the flow characteristics of the slag phase. Most preferably, the particulate materials are readily available in large quantities and at a low cost. Clean sand is very suitable, as is a granulated form of a final slag with a high melting point, such as a final slag from copper refining. The inventors have further found that the shielding material can form a shell in the mouth of the oven that prevents overflowing of any solid, non-melted pieces floating on the liquid in the oven. In addition, sand is a convenient and readily available source of silicon dioxide in suitable purity to achieve the desired result without interfering in any way with the process. The silicon dioxide that BE2018 / 5240 enters the slag can be easily recycled to an upstream smelting step, where the silicon dioxide typically ends up in the final spent slag by-product of the smelting furnace, which may bring further benefits. Preferably, the inert particulate solid material is distributed over a large area of the surface of the bath such that it reaches a large portion of the slag floating in the liquid bath on top of the raw solder. We prefer that the shielding material be in a finely divided form, such as a powder or granules. Applicants have found that a finely divided shape spreads more easily over the surface of the liquid bath. In an embodiment, step d) and / or step m) of the method of the present invention further comprises, before the separation of the slag and the raw solder, a flux material containing SiO 2 . An extremely suitable flux material containing SiO 2 is sand, because it is very rich in SiO 2 and because sources of sand that are low in potentially interfering other compounds are easy to find. However, applicants have identified suitable alternatives, some of which are available at even more economically attractive conditions. The method of the present invention is able to accept flux material containing, in addition to SiO 2 , specific metals such as Sn, Pb, Cu, Fe, Ni, and / or oxides thereof. These metals, even when introduced in the form of the oxides, can be recovered as part of the global process, and can therefore be upgraded at least in part. Applicants have found, for example, that lead glass ("crystal glass"), or its waste form, is a very suitable flux material for step) and / or step m), while alternative economic applications are difficult to find for this type of waste streams. Applicants have found that the cathode ray tubes (CRTs) used in older generation televisions, in computer displays and other electronic devices, or in BE2018 / 5240 radar targets are highly acceptable as a source of suitable flux material, and are advantageous in that the front face of the CRT is typically made of thick and heavy lead glass, especially when used as part of a consumer product. The inventors have found that the addition of a flux material results in a decrease in the melting temperature of the slag and / or a decrease in the viscosity of the slag (and thus an increase in fluidity) at a given temperature. We have found that, as an added benefit, significant amounts of SiO 2 also reduce the SnO 2 content of the snail by acidifying the snail and thereby driving SnO 2 out of the snail by affecting the activity of SnO 2 , this oxide easily is reduced to Sn and thus transitions to the metal phase. We have further found that adding SiO 2 to the furnace in step d) and / or step m) results in the conversion of FeO in the slag to FeO-SiO 2 , according to the following reaction: 2FeO + SiO 2 > (FeO) 2 .SiO 2 . Preferably, a sufficient conversion of FeO to (FeO) 2 -SiO 2 is obtained to reduce and preferably eliminate the risk of explosions when the slag is removed from the oven and granulated in contact with water. Under typical slag processing conditions, FeO is able to act as a catalyst to decompose water to hydrogen and oxygen, while (FeO) 2 SiO 2 is inactive for that reaction. The stoichiometric amount of SiO 2 required to convert all FeO is 1 mole SiO 2 for every 2 moles FeO, ie 0.42 grams SiO 2 for 1 gram FeO. Applicants therefore prefer to use a FeO / SiO2 weight ratio of about 2.4. In one embodiment, the method of the present invention comprises at least one of a number of additional steps in which the crude solder obtained in step d) and / or step m) BE2018 / 5240 is further treated or "updated" to become an updated solder suitable as a base material for vacuum distillation. The crude solder produced by the method of the present invention is preferably further updated to adjust its composition and then subjected to a distillation step, preferably a vacuum distillation step, in which lead is removed by evaporation and a stream remains that has been enriched to Sn. Updating of the raw solder is preferably performed in the manner described in detail in WO 2018/060202 A1. Applicants point out that steps d) and m) of the method of the present invention, in which the raw solder becomes available, are usually performed at a high temperature, usually much higher than 500 ° C, rather in the range of 700-1000 ° C. Applicants further point out that any downstream vacuum distillation for separating lead from the solder is usually conducted at an even higher temperature. The typical temperatures for removing lead from tin by vacuum distillation are at least 900 ° C, and often as high as 1100 ° C. In one embodiment, the method of the present invention further comprises step e) of cooling the raw solder to a temperature of up to 825 ° C to form a bath comprising a first supernatant scratch which becomes gravity-floating on a first liquid molten updated soldering phase. Preferably, the raw solder is cooled to a temperature of at most 820 ° C, preferably at most 800 ° C, more preferably at most 750 ° C, even more preferably at most 700 ° C, even more preferably at most 650 ° C, preferably at most 600 ° C, even more preferably at most 550 ° C, preferably at most 525 ° C, more preferably at most 500 ° C, even more preferably at most 450 ° C, at preferably at most 400 ° C, more preferably at most 370 ° C, even more preferably at most 360 ° C, preferably at most 350 ° C, with more BE2018 / 5240 preferably at most 345 ° C, even more preferably at most 330 ° C, preferably at most 320 ° C, more preferably at most 310 ° C. We also found that when the cooling range is wider and / or reaches a lower temperature, more of these metals come out of solution and enter the supernatant scratch. The wider the cooling range is made, the more the cooling step becomes suitable for splitting into several successive cooling steps, preferably combined with intermediate scratch removal. This has the advantage that less scratch may need to be removed globally to remove the same amount of unwanted metals, and that the total amount of scratch will contain less of the global process target metals, which are primarily lead and / or tin, but also contains the various precious metals that may be present in the solder, and in certain circumstances also the antimony (Sb) that may be present. We have also found that the cooler the coarse solder, the higher its density, which is beneficial for gravity separation from the scratch, as the scratch floats more easily on the denser liquid metal phase. Applicants therefore note that step e) of the method of the present invention is counter-intuitive. Applicants note that the ordinary artisan would prefer to keep the solder at the high temperature at which it was produced, and perhaps heat it even more, before being subjected to a vacuum distillation step for separating lead from tin. Applicants have found, however, that the cooling step e) of the process in accordance with the present invention is able, without intervention of further chemicals, to remove a significant portion of the raw solder components that are undesirable in the raw material for a vacuum distillation step. , to a supernatant scratch phase, thereby making this scratch phase available to be separated from the liquid solder phase. Applicants have found that this cooling step makes a significant contribution to the formation of a separate scratch phase rich in the unwanted components, thereby BE2018 / 5240 remains a liquid brazing phase that contains less of these undesirable components and is therefore more suitable for a vacuum distillation step in which fewer operational problems arise that are caused by the possible formation of metal-metal compounds during the distillation step. Applicants have found that the cooling step is particularly capable of lowering the copper, nickel, iron and / or zinc content in the remaining liquid brazing phase. We have also found that the cooler the raw solder, the higher its density becomes, which is beneficial for gravity separation of the scratch as the scratch floats more easily on the denser liquid solder phase. In one embodiment, the method of the present invention further comprises step g) of adding an alkali metal and / or an alkaline earth metal, or a chemical compound comprising an alkali metal and / or an alkaline earth metal, to the raw solder separated in step d) and / or step m), or on the first liquid molten updated solder phase formed in step e), to form a bath comprising a second supernatant scratch that floats on a second liquid molten updated solder phase. Preferably, step g) is performed downstream of step e), on the first liquid molten updated solder phase formed in that step e). Applicants note that step g) as part of the method in accordance with the present invention lowers the concentration of the unwanted metals in the liquid soldering phase towards vacuum distillation. However, this step g) consumes chemicals as indicated. Applicants argue that, by performing steps e) and g) in series with respect to the raw solder flow, such that the concentration of unwanted metals is further reduced, the cooling step e) brings the additional advantage that the subsequent step g) requires less chemical substances from chemical treatment. BE2018 / 5240 In an embodiment of the method of the present invention comprising step g), the method further comprises step h) of removing the second scratch from the second liquid molten updated soldering phase, thereby forming a second updated solder. The chemical (s) prescribed for stapg) behave like a base, and this base gets into the scratch that can be removed downstream. The scratch contains valuable metals, and it is economically interesting to recover these metals from the scratch phases separated from the liquid metal phases as part of the process. However, many of the known recovery methods for these metals from such scratch currents are of a pyrometallurgical nature. They are carried out at very high temperatures, so high that most of the structural steel of the equipment that comes in contact with the high temperature process streams is usually protected with refractory material. However, the chemical (s) used in stepg) and entering / entering the scratch phase is / are aggressive for the most common refractories used in the typical pyrometallurgical non-ferrous metal recovery process steps. Applicants note that the cooling step e) thereby not only contributes to keeping the content of the chemical (s) introduced in step g) low, but also contributes to the acceptability for the reuse of the scratch downstream of step g) is separated to recover valuable metals therefrom by a pyrometallurgical method. We found that in the cooling step e) mainly copper, zinc, iron and nickel can chemically bind with tin and that these compounds can float to the surface, provided that the underlying liquid stream contains sufficient lead, and thus has a sufficiently high density. We found that the chemical introduced in step g) is capable of removing some of the unwanted ones BE2018 / 5240 to bind metals, mainly copper and zinc, in a form that also easily floats to the surface as part of the second surfacing scratch. In one embodiment, the method of the present invention includes step f) of removing the first supernatant scratch from the first liquid molten updated solder phase formed in step e), thereby forming a first updated solder, the first supernatant scratch preferably is removed before performing step g), if step g) is present. We prefer to remove the scratch from each crude solder treatment step before starting the next treatment step. We have found that this has the advantage that the overall amount of scratch is smaller compared to the alternative of allowing the scratch to come together from several steps and remove all scratch together at the end of the rough solder treatment steps. A scratch also contains some tin and / or lead, and these amounts of valuable metals are thus disadvantageously removed from the metal stream fed to the intended downstream vacuum distillation step. These amounts of valuable metals also increase the burden of reworking the scratch to recover the valuable metals therein, including the entrained tin and / or lead, as well as the other metals removed from the treatment by the flow of raw solder. In one embodiment, the method of the present invention further comprises step i) of distilling the first updated solder from step f) or the second updated solder from step h), whereby lead (Pb) is removed from the solder by evaporation and a top distillation product and a bottom distillation product are obtained, preferably by vacuum distillation. Applicants have found that the distillation step i), which takes place downstream of, or in some of the embodiments part of the process of the present invention, is capable of being performed without serious risk of metal-metal bond formation inside the distillation equipment. BE2018 / 5240 The distillation step i) can be performed under very low pressures, such as no more than 50 Pa absolute, possibly no more than 10-15 Pa, and often even as low as 0.1-5 Pa, in combination with relatively high temperatures of at least at least 800 ° C, preferably at least 900 ° C. The vacuum distillation of the updated solder can be performed batchwise, and such batch vacuum distillation techniques are disclosed in CN101696475, CN104141152, CN101570826, and in Yang et al, "Recycling of metals from waste Sn-based alloys by vacuum separation", Transactions of Nonferrous Metals Society of China, 25 (2015), 1315-1324, Elsevier Science Press. The distillation under vacuum of the updated solder can also be performed in continuous mode, and such continuous distillation techniques are disclosed in CN102352443, CN104651626 and CN104593614. Preferably, the distillation is carried out as disclosed in WO 2018/060202 A1. In an embodiment of the method of the present invention comprising step i), the distillation bottoms from step i) comprise at least 0.6 wt% lead. Applicants prefer that the bottom product comprises more than 0.60 wt% lead, preferably at least 0.65 wt% lead, more preferably at least 0.70 wt% lead, even more preferably at least 0.75 wt% lead, preferably at least 0.80 wt% lead, preferably at least 1.0 wt%, more preferably at least 1.5 wt%, even more preferably at least 2.0 wt%, preferably at least 3.0 wt%, more preferably at least 4.0 wt%, even more preferably at least 5.0 wt%, and even more preferably at least at least 6.0 wt% lead. We believe that higher levels of Pb remaining in the bottoms of the distillation can act as an additional solvent, for example, for the amount of antimony that may be present in the updated solder. This solubility effect can be advantageous for the separation in the distillation step. The primary purpose of the vacuum distillation step i) is to vaporize lead (Pb) and produce a lead-containing overhead product suitable for further cleaning by conventional means for producing a BE2018 / 5240 lead product with high purity, the so-called “soft lead”. We believe that leaving an amount of lead in the bottoms of the distillation step helps accomplish that goal, by providing a liquid phase that remains attractive to many of the metals other than lead, thereby reducing the urge of these metals to become volatile, and from their tendency to escape from the liquid phase and into the overhead of the distillation step. We believe that this benefit is enhanced by leaving a higher concentration of lead in the bottoms of the distillation step. We believe that this advantage is of particular importance for any antimony present in the updated solder of the present invention. We have further found that the problems of metal-metal bond formation during the vacuum distillation of the updated solder in step i) are further alleviated by leaving a greater presence of lead in the bottoms of the distillation step. We believe that the higher amount of lead has a beneficial effect in better retaining the potentially harmful metals and in reducing their tendency to form the potentially interfering metal-metal compounds during the upstream distillation step. Without wishing to be bound by any theory, we believe this effect may be based on dilution, but we suspect that additional invoices may be involved in reducing the risk of metal-metal bond formation under the conditions that arise in the vacuum distillation step. The bottom product can be further purified in a purification step that removes at least a portion of residual impurities, such as silver, to form a purified tin stream. For example, this can be accomplished using a technique such as described in CN102534249, where a four-step crystallization operation is described for purifying a raw tin stream by removing silver. The lead distillate can be further purified in a purification step that is at least part of the residual BE2018 / 5240 removes impurities, such as arsenic and tin, to form a purified lead stream. This can be achieved, for example, using a technique such as scratching. In one embodiment, the method of the present invention includes step j) of reworking the slag from step d) and / or step m) into a pyrometallurgical production run or campaign to produce a copper concentrate. By "copper concentrate" is meant a metal product comprising at least 50 wt% copper, preferably at least 75 wt% copper. The slag recovery from step d) and / or step m) may or may not be carried out in the same equipment as the method of the present invention. The inventors have found that the reprocessing provides a means of recovering the Sn and / or Pb typically left in the slag because the slag is in phase equilibrium with the raw solder at the time when the two liquid phases of the are separated as part of step d) and / or step m). In one embodiment, the method of the present invention is operated as a campaign, and the campaign is followed in the same equipment by a campaign to produce a copper concentrate or a campaign to recover higher purity copper streams from a copper concentrate, referred to together as "A copper production campaign". A campaign preferably includes several consecutive batch runs of a similar nature. The process of the present invention is preferably operated in successive cycles, wherein, after removing at least a portion of the crude solder and / or the slag from the oven, step a) is again performed by again portion of the feed the base material into the furnace and melt the added portion of the base material to increase the volume of the liquid bath again. Steps b) and c) and d) can then be repeated. Advantageously, step b) can be performed on BE2018 / 5240 at the same time as step a), so the reducing agent can be introduced together with the base stock portion of step a). Also step c), if present, can be carried out together with step b), and optionally also together with step a). The same can be done with regard to the corresponding steps j) -m). When the target reactions are sufficiently advanced, the separation can be allowed to proceed in step d) and / or step m), and at least one of the liquid phases - at least in part - can be removed from the oven, after which again more base material in the oven may be introduced as a new iteration of step a), usually an amount of liquid remaining in the oven when the new step a) is started. At the end of the 2 or 3 final batch runs of a raw solder campaign, applicants prefer to drain only raw solder and allow the slag liquid to accumulate. A crude solder production campaign is then preferably completed by feeding, melting and reacting materials which are particularly high in lead and leaner in tin, as set out elsewhere in this document. In this manner, Sn is washed out of the slag phase and / or extracted from the furnace lining, and recovered in the final crude solder from the last batch run. Preferably, this "lead wash" is repeated several times before the equipment is released for another type of operation, such as a copper production campaign. The process of the present invention preferably starts with a substantial amount of molten metal already in the furnace, as a remnant of a previous run in the same equipment. For example, the residual metal may be the holdover from a rinse step, after a copper production campaign, as explained elsewhere in this document. Applicants have found that the method of the present invention is carried out with ease as one or more campaigns in equipment that is also capable of producing a copper concentrate containing at least 70 wt% and typically 75 wt% Cu, often black called copper, and / or in equipment that may also be capable of extracting copper flows from such copper concentrate BE2018 / 5240 to recover higher purity, which is sometimes referred to as anode-type copper. A suitable device for operating a combined operation comprising the two different campaigns is a smelting furnace. A smelting furnace has the advantage of being relatively simple and usually represents a significantly lower investment cost compared to more complex alternatives. A suitable device for processing a copper concentrate to recover an even higher purity copper stream from it is a top blown rotary converter (TBRC). Preferably, the slag from step d) and / or step m) is reprocessed in the black copper process or campaign, mainly for the recovery of their Sn and / or Pb content, and also for the recovery of copper which may be present in the snail. The Sn and Pb can be recovered in a slag from black copper production, and the copper can be recovered as part of the black copper itself. Any Fe and / or SiO 2 present in the slag from step d) and / or step m) can easily exit the process as part of the final slag from black copper production. In an embodiment of the method of the present invention that is conducted as a campaign, wherein the campaign is followed in the same equipment by a copper production, as part of the transition from the raw solder production campaign to the copper production campaign, the equipment is subjected to at least one rinse step. The rinsing step between the two campaigns aims to reduce the amount of cross contamination between the two campaigns, preferably reducing the amount of tin (Sn) lost for the raw solder production campaign and showing up as contamination in the copper production campaign. Applicants prefer to perform the rinse step as follows: 1) at the end of the raw solder campaign, as much of the slag and raw solder as possible is removed from the BE2018 / 5240 oven and relevant auxiliary equipment, usually drained as liquid products, 2) lead containing materials, preferably lead rich materials, are introduced into the furnace, any solids thereof are melted in the furnace, and the liquid contents of the furnace are stirred and contacted as much as possible with the inner walls of the furnace, which are usually formed by refractory materials, and 3) the molten lead is drained from the oven and relevant auxiliary equipment. Preferably, the rinsing step is performed two or three times. Applicants have found that the molten lead-containing material in the furnace is capable of extracting other metals that may have become adsorbed in the refractory lining of the furnace. The liquid lead is thus able to clean the oven, i.e. to remove metals other than Pb that are less desirable during a copper production campaign. When the operation in the furnace is switched again from a copper production campaign to a raw solder production campaign, the equipment may also be flushed to reduce the amount of Cu that may still be present in the equipment - and which, therefore, runs the risk of the raw solder ends up - by adding a second rinsing step after draining as much of the copper metal phase as possible. Applicants have found that such a second rinsing step is less critical and may be skipped for convenience. Preferably, such a second rinsing step includes a dilution of the raw material to at least one of the last copper production batches, to reduce the copper metal phase Cu content remaining in the oven after draining. The copper metal phase produced in this way, depending on its composition, can be reprocessed in another suitable process. In a manner of BE2018 / 5240 alternatively, the second rinsing step after a copper production campaign is performed in a similar manner to the rinsing step carried out after the raw solder production campaign, and includes the feeding of Pb-rich materials, preferably Pb scrap material, after as much of the copper metal phase as possible. drained from the oven. This addition of lead-rich materials drives more of the residual Cu present in the oven into the metal phase before the latter is removed. The metal phase produced from this second rinsing step, optionally from a succession of several of them, includes Cu along with Pb and optionally some Sn. This metal phase is tapped and, depending on its composition, is preferably reprocessed in a suitable process for the recovery of valuable metal. The inventors have found that reworking the slag from the raw solder production campaign during the black copper production campaign has the advantage that Zn, which may be present in the base materials of the raw solder production campaign, may end up in the slag of the black copper production campaign, and can be smoked out of the furnace contents during the black copper campaign. The Zn can thus be easily removed from the global process and conveniently recovered from the exhaust gases as (ZnO) dust. Any Cd present in the base materials can also be removed from the global process in the same manner and collected in the dust phase as cadmium oxide along with the ZnO. In one embodiment, the method of the present invention further comprises in step c) and / or step I) adding oxides of metals nobler than Zn, such as PbO. The inventors have found that by adding metals more noble than Zn, Zn can be converted to its oxide during step c) and / or step I), then driving this zinc oxide into the slag. The slag from step d) and / or step m), comprising the ZnO, can then be reworked into the black copper process or campaign, during which a significant portion of the ZnO can be smoked and recovered. BE2018 / 5240 During fumigation, the ZnO is usually first reduced to Zn, which evaporates and re-oxidizes in contact with the oxidizing atmosphere of the furnace, re-forming ZnO in particulate form, which is then vented out with the exhaust gases and easily recovered as ZnO dust, while the remainder of the original ZnO in the liquid phase ends up in the slag of the black copper process or campaign. Re-oxidizing the Zn in the furnace atmosphere generates heat, which can be used in part to heat the refractory furnace of the furnace, increasing the temperature of the slag and increasing the removal rate of ZnO for a given concentration in the snail. We have found that the temperature of the slag bath for setting a suitable fumigation rate is preferably at least 1200 ° C. However, we have found that the temperature should preferably not rise above 1300 ° C to reduce the wear of the furnace refractory lining. Inevitably, the metal phase still contains metals such as Zn and Cd, which are considered impurities in the raw solder. Therefore, Zn and Cd are preferably further efficiently removed from the metal phase. In one embodiment, the method of the present invention further comprises part of step c) and / or step I) fuming Zn from the metal phase in the furnace and collecting it as ZnO dust in the furnace exhaust. Preferably, this ZnO dust, which was obtained as part of step c) and / or step I) of the method of the present invention, is reprocessed in a subsequent production run for solder composition, in order to recover the Sn which is present in this ZnO substance. The inventors have found that self-reprocessing the ZnO dust is more advantageous than selling the dust as such to Zn processors because the dust typically also contains other contaminants that may be undesirable in the downstream Zn production process. For example, the ZnO substance may contain halogens, BE2018 / 5240 mainly chlorine, which preferably concentrates in this substance. Therefore, at a certain halogen content, this material is preferably rinsed before being reworked in a production run for solder composition to remove halogens, especially chlorine. In addition, we have found that cadmium (Cd) tends to concentrate in this substance, and is not usually flushed out with the halogens. When the Cd content in the ZnO dust is higher than what is acceptable in the Zn production process, it is more advantageous to reprocess the ZnO dust by adding the dust to the liquid bath of a black copper production run such that any Sn (and also Pb) present in this residual ZnO substance can at least be recovered. The inventors have found that in order to limit the total halogen content in the exhaust gas dust, ie the ZnO-containing substance, to a maximum of 10% by weight, relative to the total dry weight of the ZnO-containing substance, the base material is preferably contains limited halogens, mainly Cl, Br, F, more preferably chlorine (Cl). In an embodiment of the method of the present invention, the base material of the method comprises at most 2.0 wt% halogens, preferably less than 1.5 wt%. The halogens to be restrained as directed are the total of Cl, Br and F together, most preferably the restriction being applied to chlorine alone. The inventors have further found that halogens tend to introduce metals other than Zn into the exhaust gases, by forming chlorides that are volatile under operating conditions, such as SnCI 2 , and therefore risk losing significant amounts of valuable metals enter the exhaust gas dust, which at best are reprocessed and thus represent an inefficiency in the process. Furthermore, we have found that halogens can also lead to the formation of tacky, impermeable ejection dust on the dust filter fabric, thereby causing technical problems in the equipment for BE2018 / 5240 treating exhaust gas by condensing as liquid phases and then solidifying in cooler areas. It should be understood that all the definitions and preferences described above apply equally to all further embodiments described below. In one embodiment, the method of the present invention is performed in semi-batch mode and includes the following steps: j) introducing, after step d) and / or step m), at least an additional portion of the base material into the oven containing a metal phase liquid bath and / or molten metal oxide slag, thereby increasing the volume of liquid in the oven ; k) introducing into the oven, as a reducing agent, a material containing significant, and preferably effective, amounts of the elemental form of at least one metal less noble than Sn and Pb, preferably of elemental Fe, Al and / or Si (also referred to as Fe, Al and / or Si metal), and by their oxidation reducing tin and / or lead oxides to their elemental metal form, thereby increasing the composition of the metal phase and / or the slag phase in the oven is changed; l) optionally introducing into the furnace at least one energy source comprising a combustible material and / or at least one metal less noble than Sn and Pb, and oxidizing the combustible material and / or the at least one metal in the energy source by injecting air and / or oxygen into the furnace; m) separating the raw solder obtained in step k) and / or I) from the slag and removing at least a part of the raw solder and / or from the slag from the oven; and n) repeating the procedure from step j) or step a). The inventors have found that the composition of the slag and / or metal phase can be adjusted in the oven by introducing materials containing significant amounts of the elemental form of at least one metal less noble than Sn and Pb, preferably of elemental Fe, Al and / or Si metal, for distribution BE2018 / 5240 to change the various metals present in the furnace between the slag phase and the metal phase, which can be influenced by the oxidation of the less precious metal to an oxide. Applicants have found that this reaction of the less precious metal also adds energy to the furnace contents, energy thus not needing to be supplied by an energy source and an oxidizing agent as part of step c) and / or step I). Although for a long list of metals they are less noble than Sn and Pb, applicants prefer the use of Fe, Al and / or Si in step k), because they offer the best balance between availability, reactivity and controllability of the energy supply in the fluid bath. The applicants add that elemental aluminum (Al) is listed above as a suitable metal to be imported as part of step k), but the use of Al in this step does pose the same safety and industrial hygiene risks due to the presence of antimony (Sb) and arsenic (As), which will form somewhere downstream of the highly toxic gas stibine (SbH 3 ) or arsine (AsH 3 ), as set forth above in the context of the “cuprosiliciun” method. The use of Al can therefore only be allowed if it involves very strict and complex safety measures downstream of the method according to the present invention. Applicants have therefore determined that Al is not the preferred elemental metal to be added as part of step k), and that the preferred metals to be added in step k) are iron and silicon, the main advantage of which is to avoid these safety and industrial hygiene risks. When the method of the present invention is carried out in semi-batch mode, it means that the oven is not usually completely drained during a full campaign, for example, during a period of up to 1.5-2 years. The inventors have found that it is advantageous to leave a minimal amount of liquid bath in the oven, for example, in a typical smelting furnace with a total oven capacity of 88 tons, a BE2018 / 5240 minimum quantity of 55 tons is preferred. Applicants prefer to leave a substantial amount of liquid volume in the oven for the next process step, preferably at least 10% of the available internal volume of the oven, more preferably at least 15% volume. Applicants also prefer that the molten metal phase present in the furnace at the beginning of step a) or of step j) contain at least 1% by weight of at least one elemental metal less noble than Sn and Pb, preferably at least 2 wt%, more preferably at least 3 wt%, even more preferably at least 4 wt%, even more preferably at least 5 wt%. Applicants prefer that this minimal presence applies to the presence of iron (Fe). This has the advantage, after the addition of base material containing Sn and / or Pb oxide, that the reduction of these base material components to elemental Sn and / or Pb can start immediately after the addition of the respective oxide. An additional advantage is that this redox reaction is exothermic, and thus supplies energy in the liquid bath, which is useful for melting additional added base material, which is usually added as a solid, usually quite cold, or even at room temperature. The presence of this selected metal, in the elemental form, in the liquid bath at the beginning of step a) or step j) can therefore yield gains in terms of batch time and / or equipment productivity. In one embodiment, the method of the present invention comprises introducing, as part of step c) and / or step I), a combustible material as an additional energy source. In the presence of sufficient oxygen this entails the advantage of an additional supply of energy and / or reducing agent in the liquid bath. The additional advantage is that the addition of such combustible material can be controlled more easily and more precisely compared to the addition of the reducing agent as part of step b) or step k) and / or the energy source comprising at least one metal which is less noble then Sn and Pb. Is a suitable flammable material BE2018 / 5240, for example, wood, coal, any organic liquid, any form of petroleum or a derivative thereof, natural gas, or a mixture of at least two thereof. In one embodiment, the raw solder of the present invention comprises, relative to the total weight of the raw solder, more than 9.5 wt% tin, preferably at least 10 wt% tin, more preferably at least 11 wt %, even more preferably at least 13 wt%, preferably at least 15 wt%, more preferably at least 16 wt%, preferably at least 17 wt% tin, more preferably at least 18 wt %, even more preferably at least 19% by weight, preferably at least 20% by weight, more preferably at least 25% by weight, preferably at least 30% by weight, more preferably at least 32% by weight. %, even more preferably at least 34% by weight, even more preferably at least 36% by weight, preferably at least 38% by weight, more preferably at least 40% by weight, even more preferably at least 42% wt% tin. We have found that a higher amount of tin in the raw solder lowers the melting point of the raw solder, with the advantage that the possible downstream processes may be feasible over a wider temperature range. We have also found that the high-purity tin metal that can be recovered downstream of the raw solder of the present invention typically represents a higher economic value than most high-lead products rich in lead. A higher tin content in the raw solder of the present invention therefore increases the potential for an economical upgrading of the composition. In one embodiment, the raw solder of the present invention, relative to the total weight of the raw solder, comprises less than 69 wt% tin, preferably at most 68 wt% tin, more preferably at most 65 wt% preferably at most 62 wt%, more preferably at most 60 wt%, even more preferably at most 58 wt%, even more preferably at most 57 wt%, preferably at most 55 wt%. %, more preferably at most 53 wt%, even more preferably at most 51 wt% tin. BE2018 / 5240 In one embodiment, the raw solder of the present invention, relative to the total weight of the raw solder, comprises more than 25 wt% lead, preferably at least 28 wt% lead, more preferably at least 30 wt% even more preferably at least 32 wt%, preferably at least 34 wt%, more preferably at least 36 wt%, even more preferably at least 37 wt%, even more preferably at least 38 wt%, preferably at least 39 wt%, more preferably at least 40 wt%, even more preferably at least 41 wt% lead. We have found that a higher amount of lead in the raw solder improves any separation steps that may be performed downstream of the steps performed in the oven. We have also found that a higher lead content, which is usually accompanied by a lower tin content of the raw solder, has the advantage of lowering the solubility of copper in the raw solder. A lower copper content of the raw solder makes it possible to more easily obtain a lower copper content in the ultimately recoverable high-quality products, such as high purity tin and / or lead, for example, by vacuum distillation, thereby reducing the load associated with the downstream removal of the remaining traces of copper. In addition, a lower copper content, at least above the minimum levels prescribed below, reduces the risk of metal-metal bond formation during vacuum distillation. In one embodiment, the raw solder of the present invention, relative to the total weight of the raw solder, comprises less than 90 wt% lead, preferably at most 85 wt%, more preferably at most 80 wt%, even more preferably at most 75 wt%, preferably at most 73 wt%, more preferably at most 72 wt%, preferably at most 71 wt%, more preferably at most 70 wt%, with even more preferably at most 69 wt%, even more preferably at most 68 wt%, preferably at most 67 wt%, more preferably at most 66 wt%, even more preferably at BE2018 / 5240 at most 65 wt%, preferably at most 60 wt%, more preferably at most 55 wt%, even more preferably at most 50 wt%, preferably at most 48 wt%, with more preferably at most 46 wt%, even more preferably at most 44 wt% lead. We have found that increasing the amount of lead in the raw solder to above the stated limits does not further enhance the benefits associated elsewhere in this document with a higher amount of lead in the raw solder of the present invention. We have also found that the higher amounts of lead dilute the usually more valuable tin in the raw solder, thereby lowering the potential economic value of the raw solder. In one embodiment, the raw solder of the present invention comprises, relative to the total weight of the raw solder, more than 80 wt% tin and lead together, preferably at least 81 wt%, more preferably at least 82 wt% %, preferably at least 83% by weight, more preferably at least 84% by weight, even more preferably at least 85% by weight, even more preferably at least 86% by weight, preferably at least 87% by weight %, more preferably at least 88% by weight, even more preferably at least 89% by weight, preferably at least 89.5% by weight, more preferably at least 90% by weight, even more preferably least 90.5 wt% tin and lead together. The raw solder preferably comprises at most 96% by weight of Sn and Pb together. The raw solder of the present invention is of interest as a base material for the recovery of high purity tin and / or lead, for example, by means of a vacuum distillation step as part of the global process. High-quality end products, such as tin and lead, should preferably meet the highest standards in international trade, and therefore by-products that are not of top quality should be removed from the high-quality products to a level that is imposed through the specifications for high quality end product. A higher content of tin and lead together increases the amount of high-quality end products that BE2018 / 5240 can be recovered from the raw solder, and reduces the amount of by-product streams, usually with a lower value, that can arise from the further purification steps, for example those for the purification of the distillation products into high quality end product streams. This feature also increases process efficiency and reduces the burden associated with the disposal and / or possibly recycling of the non-top-quality by-product streams. This expense includes chemicals and energy consumption, as well as manpower and equipment investment costs. Thus, the higher tin and lead content increases economic interest in the raw solder of the present invention as a further base material for recovering high purity tin metal, and lead metal in economically acceptable forms. In one embodiment, the raw solder of the present invention, relative to the total weight of the raw solder, comprises more than 0.08 wt% copper, preferably at least 0.10 wt%, more preferably at least 0 , 20 wt%, even more preferably at least 0.50 wt%, even more preferably at least 0.75 wt%, preferably at least 1.00 wt%, more preferably at least 1, 25 wt%, even more preferably at least 1.50 wt%, even more preferably at least 1.65 wt% copper, preferably at least 1.75 wt% copper, more preferably at least 1.85 wt%, preferably at least 1.90 wt%, more preferably at least 1.95 wt%, even more preferably at least 2.0 wt%, even more preferably at least 2.1 wt%, preferably at least 2.2 wt%, more preferably at least 2.3 wt%, even more preferably at least 2.4 wt%, preferably at least 2.5 wt%, more preferably at least 3 wt%, even more preferably at least 3.5 wt %, preferably at least 4.0 wt%, more preferably at least 4.5 wt%, even more preferably at least 5.0 wt% copper. We have found that the amounts of copper indicated above can be left in the raw solder of the present invention without significant impact on the usability of the raw solder after updating [hereinafter: “updated BE2018 / 5240 solder ”]. The raw solder can be used after updating as a further base material for a vacuum distillation step without significantly reducing or nullifying the effect obtained by the present invention, ie without increasing the risk of a vacuum distillation step being performed on the updated solder, not longer be able to operate in a continuous mode for a long time without encountering problems of copper-containing metal-metal compounds interfering with the vacuum distillation operations. We have found that the identified problems can be reduced to a practical and economically acceptable level if the small amounts of copper, as directed, remain in the raw solder of the present invention, as prescribed, when used after processing as a base material for the vacuum distillation step. In one embodiment, the raw solder of the present invention, relative to the total weight of the raw solder, comprises less than 11 wt% copper, preferably at most 10 wt% copper, preferably at most 9 wt%, more preferably at most 8 wt%, even more preferably at most 7 wt%, even more preferably at most 6 wt% copper, preferably at most 5.5 wt%, more preferably at most 5 wt%, even more preferably at the most 4.5 wt% copper. We have found that the lower the concentration of copper in the raw solder of the present invention, the lower the risk of metal-metal bond formation when the updated solder is subjected to vacuum distillation. We have further found that the lower the presence of copper in the raw solder of the present invention, the lower the concentration of copper in the product streams obtained from the downstream vacuum distillation. This alleviates the burden associated with the further purification steps by removing copper from these streams on their path to become high quality end products, in particular in terms of consumption of chemicals potentially used in these downstream BE2018 / 5240 purification steps and in terms of the amounts of by-products that are formed. These by-product streams are preferably recycled to an upstream step of the process of the present invention, and may still contain the chemicals that may have been used in the purification step. Thus, this feature also has an advantage in terms of reducing the potentially deleterious effects of these chemicals in this recycling operation, such as by attacking the refractory in an upstream pyrometallurgical step. In one embodiment, the metal mixture of the present invention, relative to the total weight of the raw solder, comprises less than 0.7 wt% zinc, preferably at most 0.69 wt% zinc, more preferably at most 0 .68 wt.%, Preferably at most 0.65 wt.%, More preferably at most 0.63 wt.%, Even more preferably at most 0.60 wt.%, Even more preferably at most 0.580 wt%, preferably at most 0.570 wt%, preferably at most 0.560 wt%, preferably at most 0.550 wt%, more preferably at most 0.540 wt%, preferably at most 0.50 wt. %, more preferably at most 0.40 wt%, even more preferably at most 0.30 wt%, even more preferably at most 0.20 wt%, preferably at most 0.10 wt%. %, more preferably at most 0.08 wt%, even more preferably at most 0.06 wt%, even more preferably at most 0.05 wt% zinc. We have found that vacuum distillation performed on the raw solder of the present invention after updating, i.e. the updated solder, can be particularly sensitive to the presence of zinc. Zinc is capable of forming metal-metal compounds, and can therefore contribute to the problem addressed by the present invention. Zinc is also a free volatile metal, and zinc present may also become at least part of the vapor phase in the distillation equipment. The heating in the distillation equipment is very often provided electrically, by sending an electric current through heating electrodes within the BE2018 / 5240 distillation equipment. We found that checking the presence of zinc within the prescribed limits reduces the risk of electric arcs being drawn between two points of these heating electrodes that are close to each other and between which there is a voltage difference. Such electric arcs represent a short circuit in the electrical circuit of the heating system, and are often a cause of the equipment suddenly switching off. In case of absence or defect of fuses, they can even cause damage to the transformer and the AC / DC converter in the electrical system. The electric arcs damage and may even damage the electrodes and may also burn through the oven wall, especially when drawn between an electrode and the oven wall. In one embodiment, the crude solder of the present invention, relative to the total weight of the crude solder, comprises at least 0.0001 wt% zinc, preferably at least 0.0005 wt%, more preferably at least 0 0.0010 wt%, even more preferably at least 0.0050 wt%, preferably at least 0.010 wt%, more preferably at least 0.02 wt%, even more preferably at least 0.03 wt% .% zinc. We have found that it is not necessary to remove zinc to levels below the prescribed limits to sufficiently alleviate the problems zinc may cause during the vacuum distillation of the updated solder of the present invention. We have found that small amounts of zinc, as required, can therefore be left in the raw solder which is used as a raw material for vacuum distillation after processing. We have found that when the zinc content is within the stated limits in the raw solder of the present invention, the intended low levels of zinc in the top quality purified metal final products can be easily achieved. In one embodiment, the raw solder of the present invention, relative to the total weight of the BE2018 / 5240 raw solder, less than 2.80 wt% nickel, preferably at most 2.755 wt% nickel, more preferably at most 2.750 wt%, preferably at most 2.745 wt%, more preferably at most 2,742 wt%, even more preferably at most 2,741 wt%, even more preferably at most 2,740 wt%, preferably at most 2,730 wt%, more preferably at most 2,720 wt%, with even more preferably at most 2.710 wt%, preferably at most 2.6 wt%, more preferably at most 2.4 wt%, even more preferably at most 2.2 wt%, preferably at most 2, 0 wt%, more preferably at most 1.5 wt%, even more preferably at most 1.0 wt%, preferably at most 0.8 wt%, more preferably at most 0.75 wt %, even more preferably at most 0.7% by weight of nickel. Nickel is a metal that is present in many raw materials that are available for the recovery of non-ferrous metals, especially in secondary raw materials, and especially in end-of-life materials. It is therefore important in the recovery of non-ferrous metals that the process is able to deal with the presence of nickel. In addition, the pyrometallurgical processes for the recovery of non-ferrous metals often consume significant amounts of iron as a process chemical. It is advantageous to also be able to deal with these types of chemical process substances. It is also advantageous to be able to use secondary ferrous materials for this purpose. In addition to large amounts of iron, these materials can also contain smaller but significant amounts of nickel. Nickel is also a metal that can form metal-metal bonds during a downstream vacuum distillation step. We have found that a control within the stated limits of the amount of nickel present in the raw solder of the present invention is able to sufficiently reduce the risk of the formation of nickel-containing metal-metal compounds during vacuum distillation of the updated solder. We have further found that it is more beneficial to lower the nickel content in the base material before the vacuum distillation step, for example in the updated solder, rather than removing larger amounts of nickel BE2018 / 5240 further downstream in the method. Such a downstream nickel removal step is usually carried out together with the removal of arsenic (As) and / or antimony (Sb), and entails the risk of the formation of the highly toxic gases arsine (AsH 3 ) and / or stibine (SbH 3 ). Consequently, the removal of nickel upstream of the vacuum distillation, within the limits indicated above, also reduces the risk of toxic gases being generated downstream, and thus also represents a measure for safety and industrial hygiene. In one embodiment, the metal mixture of the present invention, relative to the total weight of the raw solder, comprises at least 0.0005 wt% nickel, preferably at least 0.0010 wt%, more preferably at least 0, 0050 wt%, preferably at least 0.010 wt%, more preferably at least 0.050 wt%, preferably at least 0.1 wt%, more preferably at least 0.2 wt%, preferably at least at least 0.3 wt%, preferably at least 0.4 wt%, more preferably at least 0.5 wt%, preferably at least 0.55 wt% nickel. We found that it is not essential to remove nickel to levels below the prescribed lower limits, such as below the detection limit of 0.0001 wt%. We have found that a control within the specified limits of the amount of nickel present in the raw solder of the present invention can sufficiently reduce the risk of metal-containing metal nickel compounds during vacuum distillation of the upgraded solder, and keep the risk low for safety and industrial hygiene risk associated with the possible downstream generation of arsine and / or stibine gas, while avoiding extra effort during cleaning of the raw solder in preparation as a base material for vacuum distillation. In one embodiment, the raw solder of the present invention comprises, relative to the total weight of the raw solder, less than 5 wt% antimony (Sb), preferably at most 4.50 wt%, more preferably at most 4.00 wt%, preferably at BE2018 / 5240 at most 3.50 wt%, more preferably at most 3.25 wt%, preferably at most 3.00 wt%, more preferably at most 2.50 wt%, even more preferably at most 2.35 wt%, even more preferably at most 2.25 wt%, preferably at most 2.15 wt%, preferably at most 1.95 wt%, preferably at most 1 85 wt%, more preferably at most 1.75 wt%, even more preferably at most 1.65 wt%, even more preferably at most 1.55 wt% of antimony. We have found that antimony can be admitted into the raw solder of the present invention, within specific limits, without causing problems when the updated solder is used as a base material for vacuum distillation. We found that it is important to keep the amount of antimony below the indicated upper limit because antimony can also at least partially evaporate under the distillation conditions. If the antimony content is higher, the amount of antimony leaving the high lead overhead distillation step can become significant. To obtain the higher purity top quality lead product in accordance with demanding industry standards, this amount of antimony should be removed from this lead stream in the conventional cleaning steps downstream of the vacuum distillation step. An amount of antimony higher than the indicated limit increases the burden of these downstream cleaning steps and increases the amount of by-product streams containing the antimony. Since these by-product streams may also contain significant amounts of lead, this lead in the by-products does not enter the top quality lead product and at least reduces the effectiveness of the entire operation. In one embodiment, the raw solder of the present invention comprises, relative to the total weight of the raw solder, more than 0.15 wt% antimony (Sb), preferably at least 0.20 wt%, more preferably at least 0.25 wt%, even more preferably at least 0.35 wt%, preferably at least 0.45 wt%, more preferably at least 0.50 wt%, even more preferably least BE2018 / 5240 0.55 wt%, even more preferably at least 0.60 wt%, preferably at least 0.65 wt%, more preferably at least 0.70 wt%, preferably at least 0.75 wt%, more preferably at least 0.80 wt%, even more preferably at least 0.9 wt%, preferably at least 1.0 wt%, more preferably at least 1.1 wt. % antimony. We have found that the raw solder of the present invention may contain measurable, and even significant, amounts of antimony, within the stated limits, without this presence of antimony entailing significant disadvantages for any downstream vacuum distillation step to which the updated solder may be subjected. We have found that this provides additional freedom of action for the base material. Due to the admission of an amount of antimony in the raw solder of the present invention, the method of the present invention is able to accept raw materials in which a significant amount of antimony is present. Antimony can be present in various primary and secondary base materials for non-ferrous metals, as well as many end-of-life materials. For example, antimony may be present in lead, which has been used for plumbing since the Roman era. Such materials can now become available by building stripping, often in combination with copper, such as in drainpipes, and with tin and lead in the solder joints. Allowing an amount of antimony into the raw solder of the present invention allows the method of the present invention to accept such mixed materials at the end of their life. We have found that significant concentrations of antimony in the raw solder of the present invention can be admitted without significant difficulties for the downstream processes. In one embodiment, the raw solder of the present invention comprises, relative to the total weight of the raw solder, less than 7.5 wt% iron, preferably at most 7.00 wt% iron, more preferably at most 6.50% by weight, preferably at BE2018 / 5240 at most 6.00 wt%, more preferably at most 5.50 wt%, even more preferably at most 5.00 wt%, even more preferably at most 4.50 wt%, even more preferably at most 4.00 wt%, preferably at most 3.50 wt%, more preferably at most 3.00 wt%, even more preferably at most 2.50 wt%, with even more preferably at most 2.00 wt% iron. Iron is a metal that is present in many raw materials that are available for the recovery of non-ferrous metals, especially in secondary raw materials, and especially in end-of-life materials. Iron is also a metal that can be introduced into the process as a reducing agent. Iron is a metal that can form metal-metal compounds during vacuum distillation. We have found that a control, within the stated limits, of the amount of iron present in the raw solder of the present invention is able to sufficiently reduce the risk of the formation of ferrous metal-metal compounds during vacuum distillation of the updated solder. In one embodiment, the raw solder of the present invention, relative to the total weight of the raw solder, comprises at least 0.0005 wt% iron, preferably at least 0.0010 wt%, more preferably at least 0 0.0050 wt%, even more preferably at least 0.0100 wt%, preferably at least 0.0500 wt%, more preferably at least 0.1000 wt%, even more preferably at least 0, 1500 wt%, preferably at least 0.2000 wt%, more preferably at least 0.5 wt%, even more preferably at least 0.8 wt%, preferably at least 0.9 wt. %, more preferably at least 1.0 wt%, even more preferably at least 1.1 wt% iron. We found that it is not necessary to remove iron to levels below the prescribed limits, in particular not below the detection limit of 0.0001 wt%. We found that a control within the stated limits of the amount of iron present in the raw solder of the present invention is able to sufficiently reduce the risk of the formation of ferrous metal BE2018 / 5240 metal compounds during vacuum distillation of the updated solder, at the same time avoid unnecessary extra efforts when cleaning the raw solder in preparation for it as a raw material for a vacuum distillation step. In one embodiment, the raw solder of the present invention, relative to the total weight of the raw solder, comprises less than 1.10 wt% sulfur, preferably at most 1.09 wt% sulfur, more preferably at most 1.08 wt%, even more preferably at most 1.07 wt%, even more preferably at most 1.06 wt%, preferably at most 1.05 wt%, more preferably at most 1.04 wt%, preferably at most 1.00 wt%, more preferably at most 0.80 wt%, even more preferably at most 0.70 wt%, preferably at most 0.60 wt%, more preferably at most 0.50 wt%, even more preferably at most 0.40 wt% sulfur. We have found that the presence of sulfur in the raw solder of the present invention can cause odor problems, and may pose an industrial hygiene problem even after the raw solder has been cooled and solidified. These problems can arise during operations and during storage, but can be even more important during maintenance interventions. We therefore prefer to reduce the sulfur contents in the raw solder of the present invention to within the indicated upper limits. In one embodiment, the raw solder of the present invention comprises, relative to the total weight of the raw solder, more than 0.010 wt% sulfur, preferably at least 0.020 wt%, more preferably at least 0.030 wt%, even more preferably at least 0.050 wt%, preferably at least 0.100 wt% sulfur. We have found that it is not necessary to reduce sulfur levels to levels below the prescribed limits, in particular not to below 0.010 wt% or 100 ppm wt. BE2018 / 5240 produce effects intended by the control of the sulfur content. In one embodiment, the raw solder of the present invention comprises, relative to the total weight of the raw solder, more than 0.012 wt% bismuth, preferably at least 0.015 wt% bismuth, more preferably at least 0.02 wt% %, preferably at least 0.025% by weight, more preferably at least 0.03% by weight, preferably at least 0.04% by weight, more preferably at least 0.05% by weight, with even more preferably at least 0.06 wt%, even more preferably at least 0.07 wt%, preferably at least 0.08 wt%, more preferably at least 0.09 wt% bismuth. Optionally, the raw solder contains less than 1.5 wt% bismuth, preferably at most 1.45 wt% bismuth, preferably at most 1.40 wt%, more preferably at most 1.35 wt%, even more preferably at most 1 , 30 wt%, even more preferably at most 1.27 wt%, preferably at most 1.24 wt%, more preferably at most 1.21 wt%, preferably at most 1.1 wt%, more preferably at most 1.0 wt%, even more preferably at most 0.9 wt%, preferably at most 0.8 wt%, more preferably at most 0.6 wt. %, even more preferably at most 0.4 wt%, preferably at most 0.2 wt%, more preferably at most 0.10 wt% bismuth. We found that bismuth can be relatively volatile under the conditions of the vacuum distillation step. Part of the bismuth can therefore end up in the high-quality products, from which it must then be removed to obtain a high-quality end product in accordance with particularly demanding product specifications. This downstream step of removing contaminants typically consumes chemicals and creates a by-product stream that also contains a measure of valuable high quality product. Even if successfully recycled, these by-product streams represent process inefficiency that is advantageously reduced. BE2018 / 5240 In one embodiment, the raw solder of the present invention comprises, relative to the total weight of the raw solder, less than 3 wt% arsenic, preferably at most 2.5 wt% arsenic, more preferably at most 1 wt %, preferably at most 0.8 wt%, more preferably at most 0.6 wt%, even more preferably at most 0.4 wt%, preferably at most 0.35 wt%, with more preferably at most 0.3 wt%, even more preferably at most 0.25 wt%, preferably at most 0.2 wt%, more preferably at most 0.18 wt% arsenic. We prefer to keep the amounts of arsenic within the stated limits. This relieves the burden of removing arsenic from any of the product streams created downstream of a possible vacuum distillation step. These removal steps use chemicals and generate by-product streams that inevitably also contain certain amounts of valuable metals, such as lead and / or tin. Even if they are recycled successfully, these by-product streams represent an inefficiency in the global process, and it is advantageous to reduce them. Recycling can also pose problems caused by the other chemicals present in these by-product streams, which may, for example, have a corrosive effect on refractories used in the process equipment of the present invention, either upstream or downstream thereof, and which come into contact with hot liquid streams. In one embodiment, the crude solder of the present invention, relative to the total weight of the crude solder, comprises at least 0.01 wt% arsenic, preferably at least 0.02 wt%, more preferably at least 0.025 wt%, preferably at least 0.03 wt%, more preferably at least 0.035 wt%, even more preferably at least 0.038 wt%, even more preferably at least 0.04 wt% arsenic . This feature has the advantage that base materials containing an amount of arsenic can to a certain extent BE2018 / 5240 are accepted. We have found that the global method, including the method of the present invention, but also including any downstream steps for further cleaning, or upstream steps, is capable of handling the indicated amounts of arsenic. In addition, the inventors have found that some commercially interesting Pb and / or Sn based alloys easily accept As up to certain levels, without significant problems, and that certain variants of such alloys even benefit from the presence of As. The raw solder and method of the present invention are therefore designed to accept the presence of As in their process streams, albeit within the stated limits. In one embodiment, the raw solder of the present invention comprises, relative to the total weight of the raw solder, less than 0.5 wt% aluminum, preferably at most 0.40 wt% aluminum, more preferably at most 0.30 wt%, preferably at most 0.20 wt%, more preferably at most 0.10 wt%, even more preferably at most 0.05 wt%, preferably at most 0.04 wt .%, more preferably at most 0.03 wt%, even more preferably at most 0.025 wt%, preferably at most 0.02 wt%, more preferably at most 0.018 wt% aluminum. Aluminum is a metal that is present in many raw materials that are available for the recovery of non-ferrous metals, especially in secondary raw materials, and especially in end-of-life materials. Aluminum is also a metal that can be introduced into the process as a reducing agent. Aluminum is a metal that can form metal-metal bonds during vacuum distillation. We have found that a control, within the stated limits, of the amount of aluminum present in the raw solder of the present invention is able to sufficiently reduce the risk of the formation of aluminum-containing metal-metal compounds during vacuum distillation of the updated solder. An additional advantage is, in particular, if the raw solder is cooled, solidified and transported to one BE2018 / 5240 another location where the solder needs to be remelted in a smelting furnace before further processing, which after the introduction of oxygen, as in the smelting furnace process, readily oxidizes the aluminum to aluminum oxide, and consequently significant amounts of energy in the furnace brings. In one embodiment, the raw solder of the present invention, relative to the total weight of the raw solder, comprises at least 0.0010 wt% aluminum, preferably at least 0.0020 wt% aluminum, more preferably at least 0.0030 wt%, preferably at least 0.0040 wt%, more preferably at least 0.0050 wt%, even more preferably at least 0.0060 wt%, preferably at least 0.0070 wt %, more preferably at least 0.0080% by weight, even more preferably at least 0.0090% by weight, preferably at least 0.010% by weight, more preferably at least 0.012% by weight aluminum. We have found that it is not essential to remove aluminum to levels below the prescribed limits, in particular not below the detection limit of 0.0001% by weight. We found that a control within the stated limits of the amount of aluminum present in the raw solder of the present invention is able to sufficiently reduce the risk of aluminum-metal-metal compound formation during vacuum distillation of the updated solder, while at the same time unnecessary avoid extra efforts for cleaning the raw solder when preparing it as a raw material for a vacuum distillation step. In an embodiment of the present invention, at least part of the method is monitored and / or controlled electronically, preferably by a computer program. Applicants have found that electronically checking steps from the method of the present invention, preferably by a computer program, has the advantage of much better processing, with results that are much more predictable and closer to the objectives of the working method. For example, the control program can, for example, based on temperature measurements, if desired also measurements BE2018 / 5240 of pressure and / or liquid levels and / or in combination with the results of chemical analyzes of samples taken from process streams and / or analytical results obtained online, checking the equipment with regard to the supply or discharge of electrical energy , the supply of heat or a cooling medium, or a control of a flow rate and / or a control of pressure. Applicants have found that such monitoring or control is particularly advantageous in continuous mode steps, but may also be advantageous in batch or semi-batch steps. In addition, and preferably, the monitoring results obtained during or after performing steps in the method of the present invention are also useful for monitoring and / or controlling other steps that are part of the method of the present invention, and / or methods used upstream or downstream of the method of the present invention, as part of an overall process of which the method of the present invention is only one part. Preferably, the entire global process is monitored electronically, more preferably by at least one computer program. Preferably, the global working method is checked electronically as much as possible. Applicants prefer that the computer audit also provides for data and instructions to be passed from one computer or computer program to at least one other computer or other computer program or other module of the same computer program, for monitoring and / or checking other methods, including but not limited to the methods described in this document. EXAMPLE The attached Figure shows a flow chart of the method performed in this example. The compositions reported in this example are expressed in units of weight, and are expressed in accordance with the logic BE2018 / 5240 above in this document is set forth with regard to expressing elements in their elemental form or in their oxidized form. Samples were taken and reduced by quartering for the analysis of the granulated raw solder product. About 10 kg of raw solder granules were melted in a small oven. The molten metal was poured into a mold and the solid bar was rolled to obtain small pieces. The slag formed in equilibrium with the crude solder product was ground in a disc mill and sieved on a 200 micron screen. Representative weights of each fraction obtained were weighed for the different laboratory test. The final Sn analysis was performed by volumetric analysis, and copper, lead, zinc, iron, nickel, antimony, bismuth, aluminum, arsenic, manganese, cobalt, molybdenum, sodium, potassium, chromium and cadmium were analyzed using an inductive coupled optical emission spectrometer (English: Inductive CouPling Optical Emission Spectrometer, ICPOES), model OPTIMA 5300 V from Perkin Elmer, after being dissolved by acid dissolution. In a copper smelting furnace (shown as unit 100 in the Figure), at the end of a copper production campaign, 1 smelting furnace rinsing step was added, during which a significant amount of lead scrap was fed to the smelting furnace, melted and brought into intimate contact with as many of the the furnace coating, after which a portion of the slag phase and a portion of the metal phase were drained from the oven. The metal drained from the oven after this lead rinse step was tracked as the 1 st batch of the raw solder production (see Table 2), and was later mixed with the raw solder produced with the following batches from the same campaign. At the end of the smelting furnace rinsing step, an amount of about 30 tons of liquid metal phase remained in the smelting furnace, containing about 21 wt% Cu, about 36 wt% Sn, about 0.4 wt% Ni, and about 37 wt% Pb included. On top of that liquid metal phase, a continuous layer of about 10 tons of molten slag phase was also left behind. BE2018 / 5240 For the soldering campaign, the materials were provided with the total amounts and the overall composition shown in Table 1. The rest of the compositions, relative to the metal concentrations in the table, mainly comprised oxygen bonded in a metal oxide. The fresh raw material portion of the base material contained small amounts of organic material including carbon, and to a very small extent also bound sulfur. This sulfur content is also given as part of the compositions in Table 1. The energy source (stream 2 in the Figure) further contained, in addition to the elements listed in Table 1, essentially only Simetal. Table 1: Base material, Energy source and Reducing agent (wt%) Element Basic material Energy source Reducing wt%Rough Nice Medium Cu 1.7444 0.0100 0.02 0.5834 Sn 29.0506 0.0296 0.01 13.8088 Pb 21.8877 0.0196 0.01 0.1308 Fe 2.3440 22.8172 4.10 66.7409 Zn 2,9035 0.2207 0.21 0.2273 Ni 0.0291 0.0100 0.01 0.7452 Sb 0.5882 0.0100 0.00 0.0118 Bi 0.0429 0.0200 0.01 0.0000 Already 0.1772 0.0000 0.03 0.0000 Ash 0.0779 0.0000 0.00 0.0417 CD 0.0143 0.0100 0.00 0.0165 Total metal 58.8599 23.1475 4.40 82,3064 Pb / Sn ratio 0.7534 0.6622 1.00 0.0095 S 0.3802 0.0700 0.06 0.1537 Cl 0.3765 0.0700 0.06 0.0859 Total mass (kg) 1687037 14146 30020 182017 In the first solder batch, 13910 kg of the base material and about 500 kg of the coarse energy source were gradually introduced into the oven. The base material added at the beginning of this first soldering batch belonged to the coarse part, and was pre-sieved on a sieve with openings of BE2018 / 5240 mm. Only the part retained on the screen was used as the base material for this first batch. The 500 kg energy source was also the result after sifting over a sieve with openings of 3 mm. After a continuous layer of slag was formed in the smelting furnace, 56767 kg of the base material and 1709 kg of the fine energy source were gradually added in the slag phase, above the level of the liquid metal in the oven. All of these quantities were fine material, with a weight average particle diameter of about 2 mm, and they were gradually injected pneumatically, approximately at the level of the interface between the metal and the slag phase. During the batch, a mixture of oxygen and methane was injected into the liquid bath, the mixture having a molar O 2 / CH 4 ratio of about 2.78. During the batch, 800 kg of purified sand (SiO2) was also gradually added as a flux material. At the end of the batch, 23700 kg of solder (stream 6 in the Figure) was drained from the oven and granulated to become solder hail. After this part of the solder was drained, about 2 tons of solid slag from a copper production run was added as a shielding material, and then, at a temperature of about 1070 ° C in the oven, most of the slag phase was removed from the smelting furnace drained (as stream 5 in the Figure), granulated as a slag which was later reprocessed as part of a copper production campaign. At the beginning of the second soldering batch of this campaign, the smelting furnace contained approximately 30 tons of liquid metal with the same composition as the first solder product (see Table 2), and a small continuous layer of slag on top of the metal. Spread approximately evenly over the next 20 batches, 868710 kg of the coarse part of the base material and 695391 kg of the fine part of the base material were added, as well as 11946 kg of the coarse part of the energy source and 28311 kg of the fine part of the energy source . In addition, 182017 kg BE2018 / 5240 of the reducing agent (flow 3 in the Figure) added, as required, and spread over the batches of the entire campaign. About 15820 kg of sand was added as flux material over the different batches, and a total of 927100 kg of solder hail was drained from the melting furnace. Each time the slag phase was cast off, about 2 tons of solid slag from a previous copper production campaign was added as a shielding material before the slag phase casting. The slags were typically cast at a temperature in the range of 1062-1170 ° C, pelleted and collected for reprocessing during a subsequent copper production campaign. Throughout the campaign, a mixture of natural gas and oxygen was injected into the smelting furnace as required. The mixture had a molar O 2 / CH 4 ratio of about 2.35, resulting in the furnace atmosphere being oxidizing in nature. The exhaust gases from the smelting furnace were filtered to collect the flue gas dust. This flue gas dust (stream 4 in the Figure), which mainly contained zinc oxide, was reinjected into the smelting furnace during the same or during the next soldering batch or campaign. When the levels of Cl or Cd in the flue gas dust had reached their critical limit, the dust collected from then on during the soldering campaign was kept separate and gradually reprocessed during a subsequent copper production campaign. The compositions and amounts of solder production from the first solder batch, from the following 20 intermediate solder batches, from the total crude solder production from the 21 batches together, and from the final rinse step are shown in Table 2. BE2018 / 5240 Table 2: Production of raw solder Element (wt%) 1 st Batch 20 Next Batches Sum of 21 Batches Rinsing step Cu 21.1400 4,8361 5.2425 0.56 Sn 36,1200 53.1433 52.7190 0.03 Pb 37.3300 38,0800 37.0613 98.82 Fe 2,2200 1.7297 1.7419 - Zn 0.7000 0.3859 0.3938 0.02 Ni 0.3900 0.5045 0.5017 0.09 Sb 0.7800 0.6434 0.6468 0.06 Bi 0.2110 0.0788 0.0821 0.043 S 0.2100 0.1167 0.1190 0.07 Already 0.0130 0.0130 0.0130 - Ash 0.2000 0.2000 0.2000 - Total% 99.3140 99.7315 99.7210 99,693 Total Mass (kg) 23700 927100 950800 17500 At the end of each solder production batch, an amount of about 30 tons of metal was left in the furnace, with on top of that also kept a continuous layer of slag about 30 cm thick, representing about 15-20 tons of slag. After the final solder production campaign, all solder was drained from the smelting furnace, and the melting furnace was then cleaned in one operation by adding and melting an amount of Pb-rich material, usually lead scrap, followed by intensive contacting of the metal phase with the coating of the oven, drain and granulate the metal phase. The amount and composition of the metal phase tapped after the rinse / cleaning step is also shown in Table 2. The metal shot collected from this rinse step was reprocessed during the next soldering campaign. The solder hail produced from the batches of the campaign was transported to a solder processing plant, remelted, and heated to a temperature of about 835 ° C before being further cleaned (i.e., "updated"). At the time of remelting, sufficient high purity lead was added to the solder such that the Sn / Pb weight ratio in the solder was about 30/70. The updated solder was further processed by vacuum distillation. BE2018 / 5240 In a first cleaning step, the raw solder was cooled to 334 ° C in two steps. In the first step, the raw solder was cooled to about 500 ° C and a first scratch was removed from the surface of the molten liquid. In the second step, the raw solder was further cooled to 334 ° C and a second scratch was removed from the surface of the molten liquid. The total scratch contained most of the copper present in the raw solder. The content of Fe and Zn in the solder was also reduced by this first cleaning step. The scratch was removed as a by-product and reprocessed during a copper production campaign. In a second cleaning step, solid sodium hydroxide was added to the solder from the first cleaning step. In this treatment step, zinc was bound by the sodium hydroxide, presumably forming Na 2 ZnO 2 , and forming a separate phase which separated from the solder as a supernatant and which was removed. As a result, the zinc content in the solder was further reduced. The amount of sodium hydroxide was adjusted so that the concentration of Zn in the solder dropped to about 15 ppm by weight. The scratch formed in this step was also recycled during a copper production campaign. In a further cleaning step, downstream from the treatment step using sodium hydroxide, an amount of elemental sulfur representing about 130% stoichiometry relative to the amount of copper remaining in the solder was added to further reduce the copper content of the solder. As the elemental sulfur, a granulated form of sulfur was used which is available from Zaklady Chemiczne Siarkopol in Tarnobrzeg (PL). The sulfur reacted primarily with copper to form copper sulfides, which transitioned to another phase of supernatant scratch. This scratch was removed from the liquid solder. After this sulfur addition step, a further amount of sodium hydroxide was added again in a subsequent step to chemically bind any remaining sulfur traces to form yet another scratch. After the response was given time to BE2018 / 5240, a handful of granulated sulfur was scattered / spread on the surface of the bath. The sulfur caught fire and burned off any hydrogen that could have evolved from the liquid as a by-product of the reaction. A small amount of white sand was then scattered / spread on the bath to dry / harden the scratch. The total scratch formed in this last step was again removed from the liquid metal bath. The purified solder thus obtained contained only about 40 ppm wt. Cu and was further processed with vacuum distillation. The sulfur-containing scratch was reprocessed in a smelting furnace during a copper production campaign such that the valuable metal contained therein could be utilized. The cleaned solder was further processed using vacuum distillation, at an average temperature of 982 ° C and an average absolute pressure of 0.012 mbar (1.2 Pa). The vacuum distillation step yielded two product streams that were suitable for further purification into high-quality, high-quality products conforming to industry standards. On the one hand, as a distillate, we obtained a product stream mainly containing lead, and on the other hand, as the bottom product, we obtained a product stream mainly containing tin, together with about 1.0 wt.% Pb. The vacuum distillation was performed in continuous mode, and for a period of about three (3) years, without any blockage or clogging of the distillation equipment by the formation of metal-metal compounds. Both product streams from the vacuum distillation step continued to be fine-tuned over the full time span to form high-quality finished products in accordance with prevailing international industrial standards. Having fully described this invention, it will be apparent to those skilled in the art that the invention can be practiced with a wide range of parameters within what is claimed without departing from the scope of the invention as defined by the claims. BE2018 / 5240
权利要求:
Claims (72) [1] CONCLUSIONS A method of producing a raw solder comprising lead (Pb) and tin (Sn), according to any of claims 50 to 72, from a base material comprising at least 50% by weight of total metal, expressed as relative to the total dry weight of the base material, the total base material comprising the following metals, the amounts of each metal being expressed as the total of the metal present in the base material in any oxidized state and in the reduced metal form , and in relation to the total dry weight of the base material: • at least 2 wt% and at most 71 wt% tin (Sn), • at least 1.00 wt% and at most 10 wt% copper (Cu), • at least 0.02 wt% and at most 5 wt% antimony (Sb), • at least 0.0004 wt% and at most 1 wt% bismuth (Bi), • at most 37 wt% zinc (Zn), • at most 1 wt. % arsenic (As), and • at most 2 wt% nickel (Ni), the total base material further comprising lead (Pb) and characterized by a Pb / Sn weight ratio of at least 0.5 and at most 4.0 , and wherein at least one of tin (Sn) and lead (Pb) is at least partially present in an oxidized valent form, the method comprising the following steps: a) obtaining a liquid bath comprising a molten metal phase and / or a molten metal oxide slag in an oven by introducing at least a portion of the base material into the oven and melting the added portion of the base material; b) introducing at least one reducing agent into the oven and reducing at least a portion of the oxidized valent form from tin and / or lead to tin and / or lead metal; c) optionally introducing into the oven at least one energy source comprising a combustible material and / or at least one metal that is less BE2018 / 5240 is noble then Sn and Pb and oxidizing the combustible material and / or the at least one metal in the energy source by injecting air and / or oxygen into the furnace; d) separating the raw solder obtained in step b) and / or c) from the slag and removing at least a part of the raw solder and / or from the slag from the oven. [2] The method of claim 1, wherein the base material comprises at least 51% by weight of total metal, relative to the total dry weight of the base material. [3] The method according to any one of claims 1 to 2, wherein the base material further comprises substances or components selected from O and S atoms, for example when present in oxides and / or sulfides, any of the halogens , carbon and organic material. [4] The method of any one of claims 1 to 3, wherein the base material comprises at least 4 wt% tin, relative to the total dry weight of the base material. [5] The method of any one of claims 1 to 4, wherein the base material comprises at most 69% by weight tin, relative to the total dry weight of the base material. [6] The method of any one of claims 1 to 5, wherein the base material comprises at least 1.02 wt% copper, relative to the total dry weight of the base material. [7] The method of any one of claims 1 to 6, wherein the base material comprises at most 9% by weight copper, relative to the total dry weight of the base material. [8] The method of any one of claims 1 to 7, wherein the base material comprises at least 0.05 wt% antimony, relative to the total dry weight of the base material. [9] The method according to any of claims 1 to 8, wherein the base material is at most 4% by weight BE2018 / 5240 includes antimony, relative to the total dry weight of the base material. [10] The method of any one of claims 1 to 9, wherein the base material comprises at least 0.0005 wt% bismuth, relative to the total dry weight of the base material. [11] The method of any one of claims 1 to 10, wherein the base material comprises at most 0.8 wt% bismuth, relative to the total dry weight of the base material. [12] The method of any one of claims 1 to 11, wherein the base material comprises at most 0.8 wt% arsenic, relative to the total dry weight of the base material. [13] The method of any one of claims 1 to 12, wherein the base material comprises at most 1.7 wt% nickel, relative to the total dry weight of the base material. [14] The method of any one of claims 1 to 13, wherein the base material comprises at least 8 wt% lead, relative to the total dry weight of the base material. [15] The method of any of claims 1 to 14, wherein the base material comprises at most 80% by weight of lead, relative to the total dry weight of the base material. [16] The method of any one of claims 1 to 15, wherein the total base material is characterized by a Pb / Sn weight ratio of at least 0.52 and at most 3.5. [17] The method according to any of claims 1 to 16, wherein the method is performed in semi-batch mode and comprises the following steps: j) introducing, after step d) and / or step m), at least an additional portion of the base material into the oven containing a liquid bath of molten metal phase and / or molten metal oxide slag, thereby increasing the volume of liquid in the oven increases; BE2018 / 5240 k) introduction into the furnace, as a reducing agent, of material containing significant, and preferably effective, amounts of the elemental form of at least one metal less noble than Sn and Pb, preferably of elemental Fe, Al and / or Si, and by its oxidation reducing tin and / or lead oxides to their elemental metal form, thereby altering the composition of the metal phase and / or the slag phase in the oven; l) optionally introducing into the furnace at least one energy source comprising a combustible material and / or at least one metal less noble than Sn and Pb, and oxidizing the combustible material and / or the at least one metal in the energy source by injecting air and / or oxygen into the furnace; m) separating the raw solder obtained in step k) and / or I) from the slag and removing at least a part of the raw solder and / or from the slag from the oven; and n) repeating the procedure from step j) or step a). [18] The method of any one of claims 1 to 17, wherein the method further comprises the step of introducing, as part of step c) and / or step I), a combustible material as an additional energy source. [19] The method of any one of claims 1 to 18, wherein step a) further comprises adding lead in the oven. [20] The method of any one of claims 1 to 19, wherein the oven used in step a) and / or step j) of the method of the present invention is a melting furnace. [21] The method according to any one of claims 1 to 20, wherein the portion of the base material used in step a) and / or step j) comprises particulate solid material and comprises at most 5% by weight of particles passing through a sieve with a 2.0 mm sieve opening, also known as a Mesh 9 sieve. BE2018 / 5240 [22] The method according to any one of claims 1 to 21, further comprising the step of injecting into the liquid bath formed in step a) and / or step j) a finely divided portion of the base material, wherein the finely divided portion of the base material has an average particle size of at most 10 mm. [23] The method of claim 22, wherein the finely divided portion of the base material is injected into the liquid slag phase and over the metal phase of the liquid bath. [24] The method of claim 22 or 23, wherein the finely divided portion of the base material has an average particle size of at most 3.36 mm. [25] The method according to any one of claims 1 to 24, wherein the molten metal liquid bath obtained in step a) and / or j) is kept at a temperature of at least 975 ° C. [26] The method according to any of claims 1 to 25, wherein the molten metal liquid bath obtained in step a) and / or j) is kept at a temperature of at most 1360 ° C. [27] The method of any one of claims 1 to 26, wherein the at least one reducing agent used in step b) and / or step k) is a metallic material containing up to 25% by weight copper. [28] The method of any one of claims 1 to 27, wherein the at least one reducing agent used in step b) and / or step k) comprises a secondary base material rich in iron. [29] The method of any one of claims 1 to 28, wherein the at least one reducing agent used in step b) and / or step k) further comprises a metallic sand. [30] The method according to any of claims 1 to 29, wherein step c) and / or step I) is present. BE2018 / 5240 [31] The method of any one of claims 1 to 30, wherein the energy source of step c) and / or step I) comprises at least one metal less noble than Sn and Pb, and further comprising injecting air and / or oxygen in the liquid bath. [32] The method according to any of claims 1 to 31, wherein in step d) and / or in step m) the removal of the crude solder and / or the slag from the oven is performed by the crude solder and / or drain the snail as a liquid from the oven. [33] The method of the preceding claim further comprising the step of cooling / solidifying the tapped crude solder by contacting the crude solder with water to obtain crude solder granules. [34] The method of any one of claims 1 to 33 further comprising the step of recovering valuable metals from the slag from step d) and / or step m). [35] The method of any one of claims 1 to 34, wherein step d) and or step m) further comprises before separating the slag from the raw solder and before removing at least a portion of the slag in step d) and / or step m), adding to the oven an amount of inert particulate solid material. [36] The method of any one of claims 1 to 35 wherein step d) and or step m) further comprises, prior to the separation of the slag and the raw solder, a flux material containing SiO 2 . [37] The method of any of claims 1 to 36 further comprising the step j) of reworking the slag from step d) and / or step m) is reworked into a pyrometallurgical production run or campaign to produce a copper concentrate. [38] The method according to any of claims 1 to 37 which is carried out as a campaign, and wherein the campaign is followed in the same equipment by a campaign to produce a copper concentrate or a campaign for the BE2018 / 5240 Recovery of higher purity copper flows from a copper concentrate, referred to collectively as “a copper production campaign”. [39] The method of the preceding claim, wherein, as part of the transition from the raw solder production campaign to the copper production campaign, the equipment is subjected to at least one rinse step. [40] The method according to any of claims 1 to 39, comprising adding in step c) and / or step I) oxides of oxides of metals nobler than Zn, such as PbO. [41] The method of claim 40 further comprising as part of step c) and / or step I) fuming Zn from the metal phase in the furnace and collecting it as ZnO dust in the furnace exhaust. [42] The method of any of the preceding claims, wherein the base material comprises at most 2.0 wt% halogens. [43] The method of any of claims 1 to 42, further comprising step e) of cooling the raw solder to a temperature of up to 825 ° C to form a bath comprising a first supernatant scratch which floats by gravity on a first liquid molten updated soldering phase. [44] The method of the preceding claim, further comprising the step g) of adding an alkali metal and / or an alkaline earth metal, or a chemical compound comprising an alkali metal and / or an alkaline earth metal, to the first liquid molten updated soldering phase to to form a bath comprising a second supernatant scratch that floats by gravity on a second liquid molten updated solder phase. [45] The method of the preceding claim, further comprising the step h) of removing the second supernatant scratch from the second liquid molten updated solder phase, thereby forming a second updated solder. BE2018 / 5240 [46] The method of any one of claims 43 to 45 further comprising step f) of removing the first supernatant scratch from the first liquid molten updated solder phase formed in step e), thereby creating a first updated solder is being formed. [47] The method of claims 45 or 46, further comprising the step i) of distilling the first updated solder from stepf) and / or the second updated solder from steph), wherein lead (Pb) is removed from the solder by evaporation and a distillation overhead product and a distillation bottoms product are obtained, preferably by vacuum distillation. [48] The method of the preceding claim, wherein the distillation bottoms from step i) comprise at least 0.6 wt% lead. [49] The method according to any of the preceding claims, wherein at least part of the method is electronically monitored and / or controlled. [50] A raw solder obtainable by the method of any one of claims 1 to 42, which in addition to unavoidable impurities and relative to the total dry weight of the raw solder, comprises: • at least 9.5 wt% and at most 69 wt% tin (Sn), • at least 25 wt% lead (Pb), • at least 80 wt% tin (Sn) and lead (Pb) together , • at least 0.08 wt% and at most 12 wt% copper (Cu), • at least 0.15 wt% and at most 7 wt% antimony (Sb), • at least 0.012 wt% and at most 1.5 wt% bismuth (Bi), • at least 0.010 wt% and at most 1.1 wt% sulfur (S), • at most 3 wt% arsenic (As), • at most 2.8 wt% nickel (Ni), • at most 0.7 wt% zinc (Zn), • at most 7.5 wt% iron (Fe), • at most 0.5 wt% aluminum ( Already). BE2018 / 5240 100 [51] The crude solder according to claim 50, comprising at least 10% by weight of tin. [52] The crude solder according to claim 50 or 51, comprising at most 68% by weight of tin. [53] The crude solder according to any one of claims 50 to 52, comprising at least 28% by weight of lead. [54] The crude solder according to any one of claims 50 to 53, comprising at most 90% by weight of lead. [55] The crude solder according to any one of claims 50 to 54, comprising at least 81% by weight of tin and lead together. [56] The crude solder according to any one of claims 50 to 55, comprising at least 0.10 wt% copper. [57] The raw solder according to any one of claims 50 to 56, comprising at most 10% by weight of copper, relative to the total weight of the raw solder. [58] The raw solder according to any one of claims 50 to 57, comprising at most 0.69% by weight of zinc, relative to the total weight of the raw solder. [59] The rough solder according to any of claims 50 to 58, comprising at least 0.0001 wt% zinc, relative to the total weight of the raw solder. [60] The raw solder according to any one of claims 50 to 59, comprising at most 2,755 wt% nickel, relative to the total weight of the raw solder. [61] The raw solder according to any one of claims 50 to 60, comprising at least 0.0005 wt% nickel, relative to the total weight of the raw solder. [62] The raw solder according to any one of claims 50 to 61, comprising at most 4.50% by weight of antimony, relative to the total weight of the raw solder. BE2018 / 5240 101 [63] The raw solder according to any of claims 50 to 62, comprising at least 0.20% by weight of antimony, relative to the total weight of the raw solder. [64] The raw solder according to any one of claims 50 to 63, comprising at most 7.00 wt% iron, relative to the total weight of the raw solder. [65] The raw solder according to any of claims 50 to 64, comprising at least 0.0005 wt% iron, relative to the total weight of the raw solder. [66] The raw solder according to any one of claims 50 to 65, which comprises at most 1.09% by weight of sulfur, relative to the total weight of the raw solder. [67] The raw solder according to any one of claims 50 to 66, comprising at least 0.020 wt% sulfur, relative to the total weight of the raw solder. [68] The raw solder according to any one of claims 50 to 67, comprising at least 0.015 wt% bismuth and at most 1.45 wt% bismuth, relative to the total weight of the raw solder. [69] The raw solder according to any one of claims 50 to 68, comprising at most 2.5% by weight arsenic, relative to the total weight of the raw solder. [70] The raw solder according to any of claims 50 to 69, comprising at least 0.01 wt% arsenic, relative to the total weight of the raw solder. [71] The raw solder according to any one of claims 50 to 70, comprising at most 0.40% by weight aluminum, relative to the total weight of the raw solder. [72] The raw solder according to any one of claims 50 to 71, comprising at least 0.0010% by weight aluminum, relative to the total weight of the raw solder. BE2018 / 5240 102
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引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 GB224923A|1923-05-15|1924-11-17|Henry Edwards|Improved metallurgical treatment of tin ores, concentrates or the like| GB415181A|1933-03-23|1934-08-23|Henry Ambrose Pudsay Littledal|Improvements in hard soldering mixtures and hard soldering processes| US2329817A|1941-10-30|1943-09-21|American Smelting Refining|Process for refining metals| US4017308A|1973-12-20|1977-04-12|Boliden Aktiebolag|Smelting and reduction of oxidic and sulphated lead material| SE436045B|1983-05-02|1984-11-05|Boliden Ab|PROCEDURE FOR MANUFACTURING RABLY FROM SULFUR CONTAINING OXIDIC LEADERS| SE445361B|1984-12-12|1986-06-16|Boliden Ab|PROCEDURE FOR REPAIRING SECONDARY METAL MELTING MATERIALS COPYING| SU1638189A1|1988-10-10|1991-03-30|Уральский научно-исследовательский и проектный институт медной промышленности "УНИПРОМЕДЬ"|Charge for decopperization of tin-containing converter slags| EP0652072A1|1993-11-09|1995-05-10|Matsushita Electric Industrial Co., Ltd.|Solder| RU2094509C1|1994-08-08|1997-10-27|Институт высокотемпературной электрохимии Уральского отделения РАН|Method for production of lead of wastes| RU2094495C1|1994-10-12|1997-10-27|Институт металлургии Уральского отделения РАН|Method of processing tin-containing iron-arsenic alloys| CN100509258C|2005-07-14|2009-07-08|上海上电电容器有限公司|Low-temperature welding material| CN101570826A|2009-06-08|2009-11-04|昆明鼎邦科技有限公司|Method for multilevel vacuum distilling and separating tin-lead alloy| CN101696475B|2009-10-29|2012-08-01|昆明理工大学|Method for separating ternary alloy of lead, tin and stibium| CN102352443B|2011-10-31|2013-06-05|太仓市南仓金属材料有限公司|Method for producing zinc sulfate heptahydrate, crude tin and crude lead by using tin smelting dust| CN102534249B|2012-02-22|2013-03-06|郴州丰越环保科技股份有限公司|Method for refining tin from high-silver crude tin| JP2014024082A|2012-07-26|2014-02-06|Sumitomo Metal Mining Co Ltd|Solder alloy| CN104141152A|2014-07-28|2014-11-12|蒙自矿冶有限责任公司|Method for recycling tin from lead bullion| CN104593614A|2014-12-30|2015-05-06|郴州丰越环保科技有限公司|Method for efficiently separating lead, tin and antimony from lead-tin-antimony ternary alloy of high antimony content| CN104651626A|2015-02-05|2015-05-27|昆明鼎邦科技有限公司|Method for separating tin from tin-lead-stibium-arsenic alloy by vacuum distillation|
法律状态:
2018-12-13| FG| Patent granted|Effective date: 20181116 |
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